Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridKARTAL, Zeki/0000-0001-9739-0858
dc.contributor.authorKartal, Zeki
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:26:08Z
dc.date.available2025-03-23T19:26:08Z
dc.date.issued2021
dc.departmentSinop Üniversitesi
dc.description.abstractIn- this study, synthesis of two new heteronuclear tetracyanonickelate(II) clathrates based on 4-aminopyridine (4AP) and guest water (H2O) molecule and investigation of their structural properties were reported. These clathrates were characterized by using vibration spectroscopy, elemental, thermal analysis and single crystal X-ray diffraction (SC-XRD) techniques. Examining the elemental and spectral data of these clathrates, it was observed that the formulas [Zn(II)(4AP)(2)Ni(mu-CN)(2)(CN)(2)]center dot 6H(2)O and [Cu(II)(4AP)(4)Ni(mu-CN)(2)(CN)(2)]center dot H2O were defined their structures. General information about the structural properties of these clathrates in single crystal form has been obtained by considering the changes in the characteristic peaks of the cyanide group and the 4AP that formed them. The thermal behaviors of these clathrates were obtained by examining the temperature-dependent changes of their masses. The magnetic susceptibilities of these clathrates in single crystal form were measured with a Gouy balance. According to the data obtained using SC-XRD technique, the heterometallic [Zn(II)(4AP)(2)Ni(mu-CN)(2)(CN)(2)]center dot 6H(2)O compound has Cmcm and the heterometallic [Cu(II)(4AP)(4)Ni(mu-CN)(2)(CN)(2)]center dot H2O compound has crystal structures in the C2/c space group.
dc.description.sponsorshipKutahya Dumlupinar University, Turkey [2017/25]
dc.description.sponsorshipThe authors wishes to thank in particular Kutahya Dumlupinar University, Turkey, for the technical [Department of Physics and Chemistry; Advanced Technologies Center (ILTEM)] and financial support with the project number 2017/25. The authors acknowledge to Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.3906/kim-2011-29
dc.identifier.endpage633
dc.identifier.issn1300-0527
dc.identifier.issue3
dc.identifier.pmid34385856
dc.identifier.scopus2-s2.0-85108192248
dc.identifier.scopusqualityQ3
dc.identifier.startpage616
dc.identifier.trdizinid526094
dc.identifier.urihttps://doi.org/10.3906/kim-2011-29
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/526094
dc.identifier.urihttps://hdl.handle.net/11486/4638
dc.identifier.volume45
dc.identifier.wosWOS:000668365800010
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakTR-Dizin
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20250323
dc.subjectHofmann-type clathrates
dc.subjectHofmann-type-like clathrates
dc.subject4-aminopyridine
dc.subjectvibration spectra
dc.subjectsingle crystal X-Ray diffraction (SC-XRD) analysis
dc.titleSynthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water
dc.typeArticle

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