Synthesis, spectroscopic, thermal, crystal structure properties, and characterization of new Hofmann-Td-type complexes with 3-aminopyridine

Basit Öğe Kaydı
dc.authoridKARTAL, Zeki/0000-0001-9739-0858
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorKartal, Zeki
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:26:07Z
dc.date.available2025-03-23T19:26:07Z
dc.date.issued2021
dc.departmentSinop Üniversitesi
dc.description.abstractIn this study, synthesis of two new tetracyanocadmate(II) and tetracyanozincate(II) complexes based on 3-aminopyridine (3AP) and investigation of their structural properties were reported. These complexes were characterized by using vibration spectroscopy, elemental, thermal analysis and single crystal X-ray diffraction (SC-XRD) techniques. Investigation of the elemental, spectral and single crystal data of these complexes showed that the formulas [Cd(3AP)(2)Zn(mu(4)-CN)(4)](n) (1) and [Cd(3AP)(2)Cd(mu(4)-CN)(4)](n) (2) fully explained their crystal structure. General information about the structural and chemical properties of these complexes obtained in single crystal form was obtained by observing the changes in the characteristic peaks of the 3AP with the [Zn(mu(4)-CN)(4)](2) and [Cd(mu(4)-CN)(4)](2) structures that make up these complexes. The behaviors of these complexes against changes in temperature were obtained by examining the temperature-dependent changes of their mass. The asymmetric unit of the heterometallic complexes 1 and 2 consist of half Cd(II) ion, half M ion [M = Zn] in 1 and Cd2 in 2], two cyanide ligands and one 3AP.
dc.description.sponsorshipKutahya Dumlupinar University, Turkiye [2017/25]
dc.description.sponsorshipThe authors wish to thank in particular Kutahya Dumlupinar University, Turkiye, for the technical [Department of Physics and Chemistry; Advanced Technologies Center (ILTEM)] and financial support with the project number 2017/25. The authors acknowledge the Scientific and Technological Research Application and Research Center, Sinop University, Turkiye, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.3906/kim-2101-32
dc.identifier.endpage955
dc.identifier.issn1300-0527
dc.identifier.issue3
dc.identifier.pmid34385878
dc.identifier.scopus2-s2.0-85110946476
dc.identifier.scopusqualityQ3
dc.identifier.startpage942
dc.identifier.trdizinid526697
dc.identifier.urihttps://doi.org/10.3906/kim-2101-32
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/526697
dc.identifier.urihttps://hdl.handle.net/11486/4637
dc.identifier.volume45
dc.identifier.wosWOS:000668365800035
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakTR-Dizin
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20250323
dc.subjectHofmann-T-d-type complexes
dc.subject3-aminopyridine
dc.subjectvibration spectra
dc.subjectSC-XRD analysis
dc.titleSynthesis, spectroscopic, thermal, crystal structure properties, and characterization of new Hofmann-Td-type complexes with 3-aminopyridine
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
TR-Dizin İndeksli Yayınlar Koleksiyonu