Rhodium(0) nanoparticles supported on ceria as catalysts in hydrogenation of neat benzene at room temperature

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dc.authoridAkbayrak, Serdar/0000-0003-3858-2985
dc.contributor.authorAkbayrak, Serdar
dc.date.accessioned2025-03-23T19:41:17Z
dc.date.available2025-03-23T19:41:17Z
dc.date.issued2018
dc.departmentSinop Üniversitesi
dc.description.abstractRhodium(0) nanoparticles supported on ceria (Rh NPs/CeO2) were prepared from the reduction of Rh3+ ions on the surface of ceria in aqueous medium. Rh NPs/CeO2 catalyst was found to be highly active in hydrogenation of benzene under mild conditions. It provided a TOF value of 495 h(-1) in hydrogenation of solventless benzene under similar to 3 bar pressure of H-2 gas at 25.0 +/- 0.1 degrees C. Rh NPs/CeO2 shows superior catalytic activity over titania, zirconia and hafnia supported Rh NPs in this reaction. (C) 2018 Elsevier Inc. All rights reserved.
dc.identifier.doi10.1016/j.jcis.2018.07.011
dc.identifier.endpage464
dc.identifier.issn0021-9797
dc.identifier.issn1095-7103
dc.identifier.pmid29990781
dc.identifier.scopus2-s2.0-85049474036
dc.identifier.scopusqualityQ1
dc.identifier.startpage459
dc.identifier.urihttps://doi.org/10.1016/j.jcis.2018.07.011
dc.identifier.urihttps://hdl.handle.net/11486/6542
dc.identifier.volume530
dc.identifier.wosWOS:000442700000050
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthorAkbayrak, Serdar
dc.language.isoen
dc.publisherAcademic Press Inc Elsevier Science
dc.relation.ispartofJournal of Colloid and Interface Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectHydrogenation
dc.subjectBenzene
dc.subjectToluene
dc.subjectRhodium
dc.subjectCeria
dc.titleRhodium(0) nanoparticles supported on ceria as catalysts in hydrogenation of neat benzene at room temperature
dc.typeArticle

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