Intramolecular through-space charge transfer between benzofuran and ynone groups on a naphthalene spacer

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dc.authoridTurkmen, Yunus/0000-0002-9797-2820
dc.authoridAkdag, Akin/0000-0002-0058-905X
dc.authoridUlgut, Burak/0000-0002-4402-0033
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorCalikyilmaz, Eylul
dc.contributor.authorKaraoglu, Gozde
dc.contributor.authorDemir, Mete
dc.contributor.authorSahin, Onur
dc.contributor.authorUlgut, Burak
dc.contributor.authorAkdag, Akin
dc.contributor.authorTurkmen, Yunus Emre
dc.date.accessioned2025-03-23T19:35:41Z
dc.date.available2025-03-23T19:35:41Z
dc.date.issued2024
dc.departmentSinop Üniversitesi
dc.description.abstractWe have developed a new scaffold that exhibits an efficient intramolecular through-space charge transfer (CT). In this design, electron-rich benzofuran and electron-deficient ynone groups are placed strategically in proximity via a naphthalene spacer. Charge transfer is supported by distinct CT bands in the visible region (>500 nm) in their UV-vis absorption and emission spectra.
dc.description.sponsorshipGEBIP Award of the Turkish Academy of Sciences
dc.description.sponsorshipY. E. T. acknowledges financial support by the GEBIP Award of the Turkish Academy of Sciences. The authors acknowledge the Scientific and Technological Research Application and Research Center, Sinop University, Turkiye, for the use of the Bruker D8 QUEST diffractometer. The authors also thank Badar Munir and Merve Temel for their assistance in the characterization of compound 5c.
dc.identifier.doi10.1039/d3cc05109a
dc.identifier.endpage553
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.issue5
dc.identifier.pmid38088785
dc.identifier.scopus2-s2.0-85180106088
dc.identifier.scopusqualityQ1
dc.identifier.startpage550
dc.identifier.urihttps://doi.org/10.1039/d3cc05109a
dc.identifier.urihttps://hdl.handle.net/11486/5909
dc.identifier.volume60
dc.identifier.wosWOS:001125508500001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.relation.ispartofChemical Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectActivated Delayed Fluorescence
dc.subjectTransfer Spectra
dc.subjectPi-Complexes
dc.titleIntramolecular through-space charge transfer between benzofuran and ynone groups on a naphthalene spacer
dc.typeArticle

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