Synthesis of Hofmann-type Zn(H2O)2 Ni(CN)4•nG (G = water and 1,4-dioxane) clathrates and the determination of their structural properties by various spectroscopic methods

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dc.authoridKARTAL, Zeki/0000-0001-9739-0858
dc.authoridYAVUZ, Abdulkerim/0000-0001-5674-4429
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorKartal, Zeki
dc.contributor.authorSahin, Onur
dc.contributor.authorYavuz, Abdulkerim
dc.date.accessioned2025-03-23T19:26:08Z
dc.date.available2025-03-23T19:26:08Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new 2-dimensional cyanide-bridged coordination polymers [Zn(H2O)(2)Ni(CN)(4) 6(H2O) and Zn(H2O)(2) Ni(CN)(4) 3(C4H8O2)], which were similar to Hofmann-type clathrates, were synthesized based on [Ni(CN)(4)](2-) and Zn2+ as building blocks. These substances were synthesized as compounds in crystalline form. Thes tructures of the crystalline compounds were characterized via their spectral analyses. General information about the structures of the newly obtained Hofmann-type clathrates was obtained from their vibration spectra by considering significant changes in the vibration peaks of the cyanide group, water ligand molecule, and guest molecules (water and 1,4-dioxane). The thermal behavior of the Hofmann-type clathrates was investigated in the range of 25-500 degrees C. In addition, experimental data on the magnetic properties of the Hofmann-type clathrates were obtained using the Gouy method under normal conditions. Information on the properties of the structures of the Hofmann clathrates was obtained by applying the single crystal diffraction technique. The asymmetric unit of the first Hofmann-type clathrate contained 1 Zn(II) ion, 1 Ni(II) ion, 1 cyanide ligand, 1 water ligand molecule, and 2 guest water molecules. The asymmetric unit of the second Hofmann-type clathrate contained 1 Zn(II) ion, 1 Ni(II) ion, 2 cyanide ligands, 1 water ligand molecule, and 2 half guest 1,4-dioxane molecules.
dc.description.sponsorshipKutahya Dumlupinar University [2017/25]
dc.description.sponsorshipThe authors wish to particularly thank Kutahya Dumlupinar University for their technical support (Department of Physics and Chemistry) and financial support under project number 2017/25. The authors acknowledge the Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of their Bruker D8 QUEST diffractometer.
dc.identifier.doi10.3906/kim-1906-26
dc.identifier.endpage1621
dc.identifier.issn1300-0527
dc.identifier.issue6
dc.identifier.scopus2-s2.0-85077209386
dc.identifier.scopusqualityQ3
dc.identifier.startpage1608
dc.identifier.trdizinid336104
dc.identifier.urihttps://doi.org/10.3906/kim-1906-26
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/336104
dc.identifier.urihttps://hdl.handle.net/11486/4639
dc.identifier.volume43
dc.identifier.wosWOS:000501598500008
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20250323
dc.subjectHofmann-type clathrates
dc.subjectvibrational spectra
dc.subjectsingle crystal X-ray diffraction analysis
dc.subjecthost structure
dc.subjectguest molecules
dc.titleSynthesis of Hofmann-type Zn(H2O)2 Ni(CN)4•nG (G = water and 1,4-dioxane) clathrates and the determination of their structural properties by various spectroscopic methods
dc.typeArticle

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