SPECTRAL CHARACTERIZATION AND ANTIBACTERIAL, ANTIFUNGAL, ANTIVIRAL ACTIVITY OF SALICYL BASED NEW SCHIFF BASES AND THEIR Co(II), Ni(II), Cu(II), Zn(II), AND Pd(II) COMPLEXES **

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dc.contributor.authorPardaeva, Dildora
dc.contributor.authorTavman, Aydin
dc.contributor.authorGurbuz, Demet
dc.contributor.authorHacioglu, Mayram
dc.contributor.authorYilmaz, Fatima Nur
dc.contributor.authorSahin, Onur
dc.contributor.authorTan, A. Seher Birteksoz
dc.date.accessioned2025-03-23T19:26:34Z
dc.date.available2025-03-23T19:26:34Z
dc.date.issued2024
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new salicyl based Schiff bases derived from 3,5-dichlorosalicylaldehyde and 4-(chloro/ tert - butyl)-2-aminophenols ( H 2 L 1 and H 2 L 2 ) and their complexes with cobalt(II), nickel(II), copper(II), zinc(II), and palladium(II), {[M( L n )(H 2 O)]center dot x H 2 O, M(II) = Co(II) ( n = 1, 2; x = 1), Ni(II) ( n = 1, x = 2; n = 2, x = 0), Cu(II) ( n = 1, 2; x = 0), Zn(II) ( n = 1, 2; x = 0); K[Pd( L n )Cl]; n = 1, 2}, were synthesized and characterized. The structural characteristics of the complexes were examined by means of elemental analysis, molar conductivity, magnetic moment, thermogravimetric analysis (TGA), UVvisible, FT -IR, and NMR spectroscopy. In addition, the crystal structures of H 2 L 1 and H 2 L 2 were determined by X-ray single diffraction measurements. All the complexes are non -electrolyte with 1:1 M:L ratio. Antibacterial and antifungal activity of the compounds was evaluated against six bacteria and three fungi. In general, all the compounds showed moderate antimicrobial activity. Some of the complexes exhibited higher activity towards some microorganisms than the ligands. Antiviral activity of the compounds was tested against Parainfluenza Type -2 virus. The fact that H 2 L 2 has a higher antiviral effect than H 2 L 1 can be evaluated as that the tert -butyl group promotes the antiviral effect.
dc.description.sponsorshipScientific Research Projects Coordination Unit of Istanbul University-Cerrahpasa [36370]
dc.description.sponsorshipThis work was supported by Scientific Research Projects Coordination Unit of Istanbul University- Cerrahpasa, Project number 36370.
dc.identifier.doi10.33224/rrch.2024.69.1-2.10
dc.identifier.endpage96
dc.identifier.issn0035-3930
dc.identifier.issue1-2
dc.identifier.scopus2-s2.0-85192961686
dc.identifier.scopusqualityQ4
dc.identifier.startpage83
dc.identifier.urihttps://doi.org/10.33224/rrch.2024.69.1-2.10
dc.identifier.urihttps://hdl.handle.net/11486/4728
dc.identifier.volume69
dc.identifier.wosWOS:001265348800011
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherEditura Acad Romane
dc.relation.ispartofRevue Roumaine De Chimie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20250323
dc.subjectTransfer Radical Polymerization
dc.subjectAntimicrobial Activity
dc.subjectMetal-Complexes
dc.subjectSquare-Planar
dc.subjectBiological-Activity
dc.subjectCrystal-Structure
dc.subjectWater Clusters
dc.subjectMannich-Bases
dc.subjectRuthenium
dc.subjectNickel(Ii)
dc.titleSPECTRAL CHARACTERIZATION AND ANTIBACTERIAL, ANTIFUNGAL, ANTIVIRAL ACTIVITY OF SALICYL BASED NEW SCHIFF BASES AND THEIR Co(II), Ni(II), Cu(II), Zn(II), AND Pd(II) COMPLEXES **
dc.typeArticle

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