Crystal structure and Hirshfeld surface analysis of 2,2′{(1 E,1′E)-[ethane-1,2-diyibis(azanylyunene)]-bis(methanylylidene)}bis[4-(traluorometnoxy)-phenol]copper(II) hydroquinone hermsoiyate

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dc.authoridKansiz, Sevgi/0000-0002-8433-7975
dc.authoridFritsky, Igor/0000-0002-1092-8035
dc.authoridMeral, Seher/0000-0002-6309-8936
dc.authoridDege, Necmi/0000-0003-0660-4721
dc.contributor.authorKansiz, Sevgi
dc.contributor.authorMeral, Seher
dc.contributor.authorDege, Necmi
dc.contributor.authorAgar, Aysen Alaman
dc.contributor.authorFritsky, Igor O.
dc.date.accessioned2025-03-23T19:32:09Z
dc.date.available2025-03-23T19:32:09Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractIn the title complex, [Cu(C18H12F6N2O4)]center dot 0.5C(6)H(6)O(2), the Cu-II ion has a square-planar coordination geometry, being ligated by two N and two O atoms of the tetradentate open-chain Schiff base ligand 6,6'-{(1E,1'E)-[ethane-1,2-diyl-bis (azanylylidene)] bis (methanylylidene)}bis [2-(trifluoromethoxy) phenol].The crystal packing is stabilized by intramolecular O-H center dot center dot center dot O and intermolecular C-H center dot center dot center dot F, C-H center dot center dot center dot O and C-H center dot center dot center dot pi hydrogen bonds. In addition, weak pi-pi interactions form a three-dimensional structure. Hirshfeld surface analysis and two-dimensional fingerprint plots were performed and created to analyze the intermolecular interactions present in the crystal, indicating that the most important contributions for the crystal packing are from F center dot center dot center dot H/H center dot center dot center dot F (25.7%), H center dot center dot center dot H (23.5%) and C center dot center dot center dot H/H center dot center dot center dot C (12.6%) interactions.
dc.description.sponsorshipOndokuz Mayis University [PYO.FEN.1906.19.001]
dc.description.sponsorshipFunding for this research was provided by: Ondokuz Mayis University (award No. PYO.FEN.1906.19.001).
dc.identifier.doi10.1107/S2056989019014294
dc.identifier.endpage+
dc.identifier.issn2056-9890
dc.identifier.pmid31709098
dc.identifier.scopus2-s2.0-85074787278
dc.identifier.scopusqualityN/A
dc.identifier.startpage1729
dc.identifier.urihttps://doi.org/10.1107/S2056989019014294
dc.identifier.urihttps://hdl.handle.net/11486/5429
dc.identifier.volume75
dc.identifier.wosWOS:000495397100028
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherInt Union Crystallography
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20250323
dc.subjectcrystal structure
dc.subjectcopper (II)
dc.subjectsalentype Schiff base
dc.subjectHirshfeld surface
dc.titleCrystal structure and Hirshfeld surface analysis of 2,2′{(1 E,1′E)-[ethane-1,2-diyibis(azanylyunene)]-bis(methanylylidene)}bis[4-(traluorometnoxy)-phenol]copper(II) hydroquinone hermsoiyate
dc.typeArticle

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