Metal-free, zinc(II) and lead(II) phthalocyanines functioning with 3-(2H-benzo[d][1,2,3]triazol-2-yl)-4-hydroxyphenethyl methacrylate groups: Synthesis and investigation of photophysical and photochemical properties

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dc.authoridPiskin, Mehmet/0000-0002-4572-4905
dc.authoridBayrak, Riza/0000-0002-0398-7694
dc.contributor.authorDemirbas, Umit
dc.contributor.authorPiskin, Mehmet
dc.contributor.authorBarut, Burak
dc.contributor.authorBayrak, Riza
dc.contributor.authorDurmus, Mahmut
dc.contributor.authorKantekin, Halit
dc.date.accessioned2025-03-23T19:37:47Z
dc.date.available2025-03-23T19:37:47Z
dc.date.issued2016
dc.departmentSinop Üniversitesi
dc.description.abstractIn this study, the synthesis and characterization of 3-(2H-benzo[d][1,2,3]triazol-2-yl)-4-hydroxyphenethyl methacrylate substituted novel phthalonitrile compound and its peripherally substituted zinc(II) lead(II) and metal-free phthalocyanine derivatives were performed for the first time. This novel compounds were characterized by obtained data from general spectroscopic methods such as FT-IR, H-1 NMR, C-13 NMR and mass. The photophysical and photochemical properties of these phthalocyanines were investigated in N,N-dimethylformamide solutions for determination of their photosensitizing abilities in photocatalytic applications such as photodynamic therapy. The lead(II) phthalocyanine complex did not produce any fluorescent in N,N-dimethylformamide because of the heavy atom effect of bigger lead atom. The fluorescence quantum yields of studied zinc(II) and metal-free phthalocyanines were found to quite higher than unsubstituted zinc(II) phthalocyanine due to substitution of the phthalocyanine skeleton. The influence of substituent and variety of the central metal ions on spectroscopic, photophysical and photochemical properties were also determined and compared. (C) 2016 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.synthmet.2016.06.026
dc.identifier.endpage285
dc.identifier.issn0379-6779
dc.identifier.scopus2-s2.0-84978058394
dc.identifier.scopusqualityQ1
dc.identifier.startpage276
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2016.06.026
dc.identifier.urihttps://hdl.handle.net/11486/6011
dc.identifier.volume220
dc.identifier.wosWOS:000383811300035
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofSynthetic Metals
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectPhthalocyanine
dc.subjectBenzotriazole
dc.subjectPhotosensitizer
dc.subjectPhotophysical
dc.subjectPhotochemical
dc.titleMetal-free, zinc(II) and lead(II) phthalocyanines functioning with 3-(2H-benzo[d][1,2,3]triazol-2-yl)-4-hydroxyphenethyl methacrylate groups: Synthesis and investigation of photophysical and photochemical properties
dc.typeArticle

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