Investigation of Electrochemical Behaviour of 3-Allyl-4-Hydroxy-3'-4'- Dimethylazobenzene

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dc.contributor.authorMenek, Necati
dc.contributor.authorBaşaran, Serpil
dc.contributor.authorKaraman, Yeliz
dc.contributor.authorTopçu, Saim
dc.date.accessioned2014-08-25T11:39:59Z
dc.date.available2014-08-25T11:39:59Z
dc.date.issued2013
dc.description.abstractThe reductive voltammetric and polarographic behaviour of the 3-allyl-4-hydroxy-3'-4' dimethylazobenzene at a hanging mercury drop electrode (HMDE) and static mercury drop electrode (SMDE) has been studied in Britton-Robinson (B-R) buffers in the pH range of 2.0-12.0. The 3-allyl-4-hydroxy-3'-4' dimethylazobenzene gave one voltammetric and polarographic peak, corresponding to the reduction of the azo group to hydrazo and amine. The reduction process was found to be dependent on the pH of the supporting electrolyte. The reduction of the azo group to amino group in acidic media and hydrazo step in neutral and basic media was observed. From the observation an electrode reaction mechanism has been suggested for the compound.
dc.identifier.citationMenek, N., Başaran, S., Karaman, Y., Topçu, S. "Investigation of Electrochemical Behaviour of 3-Allyl-4-Hydroxy-3'-4'- Dimethylazobenzene". International Journal of Electrochemical Science, 8(2013)6399-6407.
dc.identifier.issn1452-3981
dc.identifier.scopus2-s2.0-84878732376
dc.identifier.urihttp://www.electrochemsci.org/papers/vol8/80506399.pdf
dc.identifier.urihttps://hdl.handle.net/11486/448
dc.language.isoen
dc.publisherInternational Journal of Electrochemical Science
dc.relation.publicationcategoryMakale - Kategorisiz
dc.subjectVoltammetry
dc.subjectPolarography
dc.subjectAzo dyes
dc.subjectReduction mechanism
dc.titleInvestigation of Electrochemical Behaviour of 3-Allyl-4-Hydroxy-3'-4'- Dimethylazobenzene
dc.typeArticle

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