Self-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blue

Basit Öğe Kaydı
dc.authoridSayin, Ulku/0000-0002-5098-1578
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridBingol, Haluk/0000-0002-6466-6851
dc.contributor.authorFindik, Mukerrem
dc.contributor.authorUcar, Asuman
dc.contributor.authorColak, Alper Tolga
dc.contributor.authorSahin, Onur
dc.contributor.authorBingol, Haluk
dc.contributor.authorSayin, Ulku
dc.contributor.authorKocak, Nuriye
dc.date.accessioned2025-03-23T19:38:18Z
dc.date.available2025-03-23T19:38:18Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractA novel organic-inorganic hybrid of 2,2'-bipyridyl (2,2'-bipy) linked covalently with the first inorganic framework based on boron-containing Keggin-type heteropolymolybdate anion [BMo12O40](5-) has been hydrothermally synthesized in aqueous solution. The crystal structure was fully characterized by elemental analyses, single crystal X-ray diffraction, Fourier-transform infrared spectrum (FT-IR), powder X-ray diffraction (XRD), Ultraviolet-visible spectroscopy (UV-Vis) and electron paramagnetic resonance (EPR) analysis. The catalytic performance of the synthesized catalyst was studied in degradation of methylene blue (MB) at ambient temperature. The catalyst exhibited excellent degradation against MB with a rate constant of 0.506/m, which was much higher than those by other polyoxometalate catalysts. Moreover, it was found to be easily separated from the reaction solution and recycled up to five times without significant loss of degradation activity. (C) 2019 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipNecmettin Erbakan University Research Foundation [151210002]
dc.description.sponsorshipThe authors thank the Necmettin Erbakan University Research Foundation (151210002) for the financial support of this study. The authors acknowledge Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1016/j.poly.2018.12.043
dc.identifier.endpage237
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-85060091565
dc.identifier.scopusqualityQ2
dc.identifier.startpage229
dc.identifier.urihttps://doi.org/10.1016/j.poly.2018.12.043
dc.identifier.urihttps://hdl.handle.net/11486/6121
dc.identifier.volume160
dc.identifier.wosWOS:000459518800030
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectPolymcometalate
dc.subjectHeteropolymolybdate
dc.subjectCatalytic degradation
dc.subjectMethylene blue
dc.subjectSingle crystal structure
dc.titleSelf-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blue
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu