Synthesis, crystal structure and spectroscopic studies of a new silver complex derived from [1-(3-pyridinyl) ethanone]

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dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.authoridAlp, Meryem/0000-0001-6821-6252
dc.contributor.authorCelik, Sibel
dc.contributor.authorAtilgan, Abdullah
dc.contributor.authorAlp, Meryem
dc.contributor.authorYurdakul, Senay
dc.contributor.authorDemircioglu, Zeynep
dc.contributor.authorOzdemir, Namik
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:39:20Z
dc.date.available2025-03-23T19:39:20Z
dc.date.issued2023
dc.departmentSinop Üniversitesi
dc.description.abstractIn this work, a new silver (I) complex, [Ag(3-pye)2(H2O)](NO3) where 3-pye=1-(3-pyridinyl) ethanone, has been synthesized and characterized by elemental analyses, FT-IR, fluorescence spectroscopy, and single X-ray crystallography. The X-ray diffraction analysis revealed that the Ag(I) complex crystallized in the monoclinic system with the C2/c space group. Computational studies were performed using DFT approache on the present complex to get insight into the structural parameters, spectral characteristics and electronic properties. The characterization results were found to be consistent with the proposed structure of the complex, and the DFT approach supported the experimental results. Also, Hirshfeld surface analysis was used to identify the non-covalent interactions within the crystal structure as well as to visualize the conformity of the crystal structure.
dc.identifier.doi10.1016/j.molstruc.2023.136468
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85169044621
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2023.136468
dc.identifier.urihttps://hdl.handle.net/11486/6321
dc.identifier.volume1294
dc.identifier.wosWOS:001067569400001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCrystal structure of silver(I) complex
dc.subjectVibrational spectra
dc.subjectDFT
dc.subjectElectronic properties
dc.subjectPhotoluminescence
dc.titleSynthesis, crystal structure and spectroscopic studies of a new silver complex derived from [1-(3-pyridinyl) ethanone]
dc.typeArticle

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