Design and construction of six coordination polymers with imidazole-4,5-dicarboxylate ligand

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dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.authoridErer, Hakan/0000-0003-3540-8797
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorErer, Hakan
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:41:31Z
dc.date.available2025-03-23T19:41:31Z
dc.date.issued2015
dc.departmentSinop Üniversitesi
dc.description.abstractSix new metal-organic frameworks based on a rigid multifunctional ligand imidazole 4,5-dicarboxylic acid (H(3)idc), namely, [Zn-3(mu(3)-idc)(mu(5)-idc)](n) (1), {[Zn-3(mu(3)-idc)(2)(H2O)(dpeten)](n)center dot 2H(2)O}(n) (2), [Zn(mu-Hidc)-( mu-obix)(0.5)](n) (3), [Zn-4(mu-Hidc)(4)(mu-mbix)(2)](n) (4), {[Cd-5(mu(5)-idc)(2)(mu(4)-Hidc)(2)(H2O)(2)]center dot 2H(2)O}(n) (5) and [Cd-2(mu(3)-Hidc)(2)(mu-obix)](n) (6) (H(3)idc = imidazole-4,5-dicarboxylic acid, obix = 1,2-bis(imidazol-1-yl-methyl)-benzene, mbix = 1,3-bis(imidazol-1-yl-methyl)-benzene and dpeten = 1,2-di(pyridin-4-yl)ethene), have been constructed under hydro(solvo)thermal conditions and structurally characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction (PXRD) and thermal analyses (TG, DTA, DSC) techniques. In these compounds, the ligand, H(3)idc, exhibits different coordination modes, constructing various architectures by bridging a variety of metal ions or polynuclear clusters. All of these coordination polymers exhibited intense fluorescent emissions in the solid state at room temperature. Furthermore, topological properties were studied. (C) 2015 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.ica.2015.05.003
dc.identifier.endpage23
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84930204785
dc.identifier.scopusqualityQ2
dc.identifier.startpage14
dc.identifier.urihttps://doi.org/10.1016/j.ica.2015.05.003
dc.identifier.urihttps://hdl.handle.net/11486/6601
dc.identifier.volume434
dc.identifier.wosWOS:000358299700003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCoordination polymers
dc.subjectImidazole-4,5-dicarboxylate complexes
dc.subjectBis(imidazole) linkers
dc.subject1,2-Di(pyridin-4-yl)ethene complexes
dc.titleDesign and construction of six coordination polymers with imidazole-4,5-dicarboxylate ligand
dc.typeArticle

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