Gas adsorption/separation properties of metal directed self-assembly of two coordination polymers with 5-nitroisophthalate

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dc.authoridArici, Mursel/0000-0001-8527-1587
dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.authoridkeskin, seda/0000-0001-5968-0336
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorArici, Mursel
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorKeskin, Seda
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:40:58Z
dc.date.available2025-03-23T19:40:58Z
dc.date.issued2014
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new coordination polymers, namely, [Co(mu-nip)(mu-bpe)] (n) and [Zn(mu-nip)(mu-bpe)](n) (2) (nip: 5-nitroisophthalate, bpe: 1,2-bis(4-pyridyl)ethane) were hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis and thermal analysis. Moreover, atomically detailed simulation studies of complex 2 for CO2/CH4 adsorption and separation were performed. Complex 1 consists of two dimensional (2D) (4,4) grid networks with the point symbol of 4(4).6(2). Complex 2 exhibits a 3-fold interpenetrating 3D framework with 6(5).8-dmp topology. Thermal properties of the complexes showed that both complexes were stable over 320 C. Simulation studies demonstrated that complex 2 can separate CO2 from CH4 at low pressures at 273 K. (C) 2013 Elsevier Inc. All rights reserved.
dc.identifier.doi10.1016/j.jssc.2013.11.010
dc.identifier.endpage286
dc.identifier.issn0022-4596
dc.identifier.issn1095-726X
dc.identifier.issue1
dc.identifier.scopus2-s2.0-84891132468
dc.identifier.scopusqualityQ1
dc.identifier.startpage280
dc.identifier.urihttps://doi.org/10.1016/j.jssc.2013.11.010
dc.identifier.urihttps://hdl.handle.net/11486/6476
dc.identifier.volume210
dc.identifier.wosWOS:000330081900043
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAcademic Press Inc Elsevier Science
dc.relation.ispartofJournal of Solid State Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subject5-Nitroisophthalate
dc.subjectCoordination polymer
dc.subjectMolecular simulations
dc.titleGas adsorption/separation properties of metal directed self-assembly of two coordination polymers with 5-nitroisophthalate
dc.typeArticle

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