A new Keggin-type polyoxometalate catalyst for degradation of aqueous organic contaminants

dc.authoridGUBBUK, ILKAY HILAL/0000-0001-7061-2588
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorOlgun, Asim
dc.contributor.authorColak, Alper Tolga
dc.contributor.authorGubbuk, I. Hilal
dc.contributor.authorSahin, Onur
dc.contributor.authorKanar, Ebru
dc.date.accessioned2025-03-23T19:39:37Z
dc.date.available2025-03-23T19:39:37Z
dc.date.issued2017
dc.departmentSinop Üniversitesi
dc.description.abstractIn this study, a new polyoxometalate,K-16[Ni(H2O)(6)](2)[BW12O40]4(center dot)48H(2)O (1) was synthesized at room temperature and characterized by X-ray single crystal diffractions, elemental analyses, IR spectra, and thermo gravimetric analyses (TGA). Crystal structure analysis reveals that compound 1 exhibits a supramolecular structure containing one Keggin-type [BW12O40](4) heteropoly anion. The catalytic properties of this molecule for the degradation of Methyl red (MR), Rhodamine B (RhB), Methyl orange (MO) and Congo red (CR) were investigated. The results show that the compound 1 is a promising catalyst candidate for dye degradation. (C) 2016 Elsevier B.V. All rights reserved.
dc.description.sponsorshipTUBITAK [BIDEB 2210-C]
dc.description.sponsorshipThanks to TUBITAK for providing scholarship to Ebru KANAR with BIDEB 2210-C programme.
dc.identifier.doi10.1016/j.molstruc.2016.12.059
dc.identifier.endpage84
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85007364599
dc.identifier.scopusqualityQ1
dc.identifier.startpage78
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2016.12.059
dc.identifier.urihttps://hdl.handle.net/11486/6398
dc.identifier.volume1134
dc.identifier.wosWOS:000394919100010
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectPolyoxometalate
dc.subjectCatalytic
dc.subjectMethyl orange
dc.subjectRhodamine B
dc.subjectMethyl red
dc.subjectCongo red
dc.titleA new Keggin-type polyoxometalate catalyst for degradation of aqueous organic contaminants
dc.typeArticle

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