Novel ruthenium(II)-N-heterocyclic carbene complexes; synthesis, characterization and catalytic application

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dc.authoridKARACA, EMINE OZGE/0000-0003-2094-9742
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridyasar, sedat/0000-0001-7285-2761
dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.contributor.authorYasar, Sedat
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorSahin, Caglar
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:40:59Z
dc.date.available2025-03-23T19:40:59Z
dc.date.issued2015
dc.departmentSinop Üniversitesi
dc.description.abstractThe synthesis of highly active ruthenium(II) catalyst based on N-heterocyclic carbene (NHC) bearing alkyl and aryl groups is reported. The complexes are easily handled in very good yields via synthesis of silver -NHC complexes and subsequent reaction with [RuCl2(p-cymene)](2) in dichloromethane (DCM) under N-2 condition. All new compounds were characterized by LC-MSMS, elemental analysis, NMR spectroscopy and X-ray diffraction. With the development of a more efficient catalytic system for transfer hydrogenation of aryl ketones and aldehydes in mind, the catalytic performance of the Ru-NHC complexes for transfer hydrogenation was investigated. (c) 2015 Elsevier B.V. All rights reserved.
dc.description.sponsorshipInonu University Research Fund [BAP gudumlu:2014-54]
dc.description.sponsorshipThis work was financially supported by Inonu University Research Fund (BAP gudumlu:2014-54)
dc.identifier.doi10.1016/j.jorganchem.2015.04.012
dc.identifier.endpage7
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-84929322166
dc.identifier.scopusqualityQ2
dc.identifier.startpage1
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2015.04.012
dc.identifier.urihttps://hdl.handle.net/11486/6487
dc.identifier.volume789-790
dc.identifier.wosWOS:000355851000001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal of Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectTransfer hydrogenation reaction
dc.subjectN-heterocyclic carbene
dc.subjectRuthenium-NHC complex
dc.subjectSilver
dc.titleNovel ruthenium(II)-N-heterocyclic carbene complexes; synthesis, characterization and catalytic application
dc.typeArticle

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