Seven-, eight-, and ten-coordinated cerium(III) with highly connective pyridine-2,4,6-tricarboxylate, oxalate, and glycine ligands

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorKhan, Islam Ullah
dc.contributor.authorSharif, Shahzad
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:35:27Z
dc.date.available2025-03-23T19:35:27Z
dc.date.issued2013
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new 3-D Ce(III) coordination polymers, [Ce-1.3(PTA)(2)(Oxa)(2)(Gly)(H2O)(2)]center dot(Gly)4H(2)O (1) and [Ce-2.6(PTA)(4)(Oxa)(2)(H2O)(10)]center dot(MeOH)7H(2)O (2) (PTA=2,4,6-pyridinetricarboxylate, oxa=oxalate and Gly=glycine), were synthesized. The oxalate in 1 and 2, generated in situ from the cleavage and chemical rearrangement of PTAH(3), assembled into mixed-ligand networks to generate 3-D frameworks. Single crystal analysis reveals that in both complexes, Ce(III) shows coordination numbers of 7 and 10 in 1 and 8 and 10 in 2. PTA adopts four kinds of coordination modes. These complexes were further characterized using elemental analysis, FTIR spectroscopy and thermogravimetric analysis.
dc.description.sponsorshipHigher Education Commission, Islamabad, Pakistan
dc.description.sponsorshipWe gratefully acknowledge the Higher Education Commission, Islamabad, Pakistan for its financial support under its Indigenous PhD Program batch (VI).
dc.identifier.doi10.1080/00958972.2013.825719
dc.identifier.endpage3125
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue17
dc.identifier.scopus2-s2.0-84883528450
dc.identifier.scopusqualityQ3
dc.identifier.startpage3113
dc.identifier.urihttps://doi.org/10.1080/00958972.2013.825719
dc.identifier.urihttps://hdl.handle.net/11486/5873
dc.identifier.volume66
dc.identifier.wosWOS:000323312600015
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectPyridine-2
dc.subject4
dc.subject6-tricarboxylic acid
dc.subjectCe(III) polymer
dc.subjectMixed ligand
dc.subjectOxalate
dc.subjectGlycine
dc.titleSeven-, eight-, and ten-coordinated cerium(III) with highly connective pyridine-2,4,6-tricarboxylate, oxalate, and glycine ligands
dc.typeArticle

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