Synthesis and characterization of new Ag(I) coordination networks based on saccharinate and bis(isopropylimidazole) ligands exhibiting very close C-H...Ag interactions

dc.authoridErer, Hakan/0000-0003-3540-8797
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorSemerci, Fatih
dc.contributor.authorSahin, Onur
dc.contributor.authorErer, Hakan
dc.date.accessioned2025-03-23T19:38:19Z
dc.date.available2025-03-23T19:38:19Z
dc.date.issued2017
dc.departmentSinop Üniversitesi
dc.description.abstractTwo Ag(l) coordination networks, formulated as [Ag(sac)(mu-bisopib)](n) (1) and [Ag(sac)(mu-pbisopix)].H2O (2), have been synthesized based on the bis(isopropylimidazole) ligands 1,4-bis(2-isopropyl-1H-imidazol-1-yl)butane (bisopib) and 1,4-bis((2-isopropyl-1H-imidazol-1-yl)methyl)benzene (pbisopix), respectively, along with saccharinate (sac) ligands. All the complexes were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction studies. The X-ray crystallographic studies of 1 and 2 revealed that the Ag(I) ions are mu-bridged by the bis(isopropylimidazole) derivative ligands to generate 1D zig-zag polymer and dinuclear structures, respectively. As far as we know, complex I shows the closest C-H...Ag interaction distance among similar literature examples. In complex 1 adjacent 1D coordination polymers are further joined by C-H...O hydrogen bonds and pi...pi interactions, generating a 3D supramolecular network. The C-H...O hydrogen bonds and C-H...pi interactions play a crucial role in the architecture of the 3D network of complex 2. Thermal decompositions and photoluminescent properties of the Ag(I) complexes are also discussed herein. (C) 2016 Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.poly.2016.11.029
dc.identifier.endpage322
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-85008187792
dc.identifier.scopusqualityQ2
dc.identifier.startpage316
dc.identifier.urihttps://doi.org/10.1016/j.poly.2016.11.029
dc.identifier.urihttps://hdl.handle.net/11486/6124
dc.identifier.volume123
dc.identifier.wosWOS:000394063300036
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCoordination polymers
dc.subjectSaccharinate complexes
dc.subjectAg(I) complexes
dc.subjectC-H...Ag interaction
dc.subjectbis(isopropylimidazole) ligands
dc.titleSynthesis and characterization of new Ag(I) coordination networks based on saccharinate and bis(isopropylimidazole) ligands exhibiting very close C-H...Ag interactions
dc.typeArticle

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