Synthesis of palladium complexes derived from imidazolidin-2-ylidene ligands and used for catalytic amination reactions

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dc.authoridyasar, sedat/0000-0001-7285-2761
dc.authoridKARACA, EMINE OZGE/0000-0003-2094-9742
dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2025-03-23T19:47:17Z
dc.date.available2025-03-23T19:47:17Z
dc.date.issued2016
dc.departmentSinop Üniversitesi
dc.description.abstractN-Aryl amination and the Buchwald-Hartwig reaction are of great synthetic and industrial interest and scientists accept their usefulness and versatility for obtaining arylamines. In this study Ag-N-heterocyclic carbene complexes were used as trans-metallation reagents for the synthesis of Pd-N-heterocyclic carbene complexes. The new Pd-N-heterocyclic carbene complexes were characterized using elemental analysis and H-1 NMR, C-13 NMR and infrared spectroscopies. The crystal structure of one, namely dichlorobis[1,3-bis(2-methylbenzyl)imidazolidin-2-yliden]palladium(II), is presented. The activity of the Pd(II) complexes in the coupling reaction of anilines or amines with bromobenzene was investigated. These complexes exhibited high catalytic activities in the direct synthesis of triarylamines and secondary amines in a single step. Copyright (C) 2016 John Wiley & Sons, Ltd.
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS (France) [109T605]; Inonu University [IUBAP: 2014/32-Gudumlu]
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS (France) [109T605] and Inonu University Research Fund (IUBAP: 2014/32-Gudumlu).
dc.identifier.doi10.1002/aoc.3541
dc.identifier.endpage1055
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue12
dc.identifier.scopus2-s2.0-84976874885
dc.identifier.scopusqualityQ1
dc.identifier.startpage1050
dc.identifier.urihttps://doi.org/10.1002/aoc.3541
dc.identifier.urihttps://hdl.handle.net/11486/7329
dc.identifier.volume30
dc.identifier.wosWOS:000388267500011
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectN-heterocyclic carbene
dc.subjectimidazolidin-2-ylidene
dc.subjectpalladium
dc.subjectamination
dc.titleSynthesis of palladium complexes derived from imidazolidin-2-ylidene ligands and used for catalytic amination reactions
dc.typeArticle

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