Dinuclear and polynuclear copper(II) complexes with 3,3′-thiodipropionate and unprecedented coordination mode

Basit Öğe Kaydı
dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.authoridArici, Mursel/0000-0001-8527-1587
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorArici, Mursel
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorSahin, Onur
dc.contributor.authorTas, Murat
dc.date.accessioned2025-03-23T19:38:21Z
dc.date.available2025-03-23T19:38:21Z
dc.date.issued2014
dc.departmentSinop Üniversitesi
dc.description.abstractThree new coordination compounds, {[Cu(mu(3)-tdp)(phen)]center dot 2H(2)O} (1), {[Cu(mu(3)-tdp)(bipy)]center dot H2O}(n) (2), [Cu(mu(3)-tdp)(bhen)(4)](NO3)(2)center dot 2H(2)O (3) [tdpH(2) = 3,3'-thiodipropionic acid, phen = 1,10-phenanthroline, bipy = 2,2'-bipyridine] were synthesized and characterized by the IR spectroscopy, elemental analysis, magnetic measurements and single crystal X-ray diffraction. Thermal behaviors and thermochromic properties of the complexes were investigated in detail. Complexes I and 2 are 1D coordination polymers while complex 3 is dinuclear structure. In complexes 1 and 2, the tdp acts as a tridentate bridging ligand to coordinate the two different Cu(H) centers to form 1D chain, which are extended into a 3D networks by hydrogen bonding and pi center dot center dot center dot pi interactions. The 3,3'-thiodipropionate ligand adopts a new coordination mode in 3. Furthermore, complex 3 changed the color from blue to green at 140 degrees C at solid state. (C) 2014 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific Research Fund of Eskisehir Osmangazi University [201219A101]
dc.description.sponsorshipThis work was supported by the Scientific Research Fund of Eskisehir Osmangazi University. Project No. 201219A101.
dc.identifier.doi10.1016/j.poly.2014.01.005
dc.identifier.endpage68
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84893234541
dc.identifier.scopusqualityQ2
dc.identifier.startpage62
dc.identifier.urihttps://doi.org/10.1016/j.poly.2014.01.005
dc.identifier.urihttps://hdl.handle.net/11486/6131
dc.identifier.volume71
dc.identifier.wosWOS:000333511700008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subject3,3 '-Thiodipropionate complexes
dc.subjectCopper(II) complexes
dc.subjectCoordination polymers
dc.subjectDinuclear complex
dc.subjectThermochromism
dc.titleDinuclear and polynuclear copper(II) complexes with 3,3′-thiodipropionate and unprecedented coordination mode
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu