Construction of rectangular microporous Cerium 3D metal organic framework for high performance energy storage devices

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dc.contributor.authorShahbaz, Muhammad
dc.contributor.authorSharif, Shahzad
dc.contributor.authorAfzal, Tayyaba Tur Rehman
dc.contributor.authorShahzad, Sundas
dc.contributor.authorShahzad, Ayesha
dc.contributor.authorSahin, Onur
dc.contributor.authorBentalib, Abdulaziz
dc.date.accessioned2026-04-25T14:19:57Z
dc.date.available2026-04-25T14:19:57Z
dc.date.issued2025
dc.departmentSinop Üniversitesi
dc.description.abstractIn modern era, there is a dire need to design a hybrid energy storage device showing properties of both supercapacitors and batteries. No doubt, various electrode materials have claimed their efficiency but metal organic frameworks (MOFs) have been focused significantly due to their salient features like high porosity and unique electrochemical properties. In this article, we report cerium-based 3D MOF having rectangular microspore sizes 0.27 x 0.52 nm for rapid and selective transport of charges to be used in hybrid energy storage devices. Structural elucidation was carried out thought single-crystal X-ray diffraction (XRD) spectroscopy and electrochemical attributes were delved via different electroanalytical tools. Three-electrode assembly in 1 M KOH electrolyte unearthed efficiency of the synthesized material and practical applications were divulged through two-electrode assembly by fabricated hybrid device. Diffusive and capacitive contribution of the material was investigated by Dunn's method. The hybrid device showed specific capacityof 101.3 C/g, specific energy of 21.11 Wh/kg and specific power of 1237.78 W/kg with cyclic stability of 99 % even after 5000 GCD cycles. Significant results proved that the material is a prospective contender for futuristic hybrid supercapacitors.
dc.description.sponsorshipHigher Education Commission of Pakistan, HEC-NRPU [20-17612/NRPU/R D/HEC/2021]; King Saud University, Riyadh, Saudi Arabia [RSPD2025R557]
dc.description.sponsorshipWe gratefully acknowledge financial assistance from the Higher Education Commission of Pakistan, HEC-NRPU project no.20-17612/NRPU/R & D/HEC/2021 and Researchers Supporting project number (RSPD2025R557) , King Saud University, Riyadh, Saudi Arabia.
dc.identifier.doi10.1016/j.jssc.2025.125394
dc.identifier.issn0022-4596
dc.identifier.issn1095-726X
dc.identifier.orcid0000-0002-8094-1489
dc.identifier.orcid0000-0001-5400-1154
dc.identifier.scopus2-s2.0-105003924457
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.jssc.2025.125394
dc.identifier.urihttps://hdl.handle.net/11486/8284
dc.identifier.volume348
dc.identifier.wosWOS:001485525900001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAcademic Press Inc Elsevier Science
dc.relation.ispartofJournal of Solid State Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20260420
dc.subject3DMOF
dc.subjectHybrid supercapacitor
dc.subjectPyridine-2,6-dicarboxylic acid
dc.titleConstruction of rectangular microporous Cerium 3D metal organic framework for high performance energy storage devices
dc.typeArticle

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