Synthesis of phosphine-containing novel Pd(II) and Ni(II) complexes: Electrochemical, photophysical and quantum chemical studies

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dc.authoridFARSAK, Murat/0000-0001-7540-7970
dc.authoridKardas, Gulfeza/0000-0002-7871-6303
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorYerlikaya, Gurbet
dc.contributor.authorTapanyigit, Eylul Busra
dc.contributor.authorGuzel, Bilgehan
dc.contributor.authorSahin, Onur
dc.contributor.authorKardas, Gulfeza
dc.date.accessioned2025-03-23T19:39:35Z
dc.date.available2025-03-23T19:39:35Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractPd(II) and Ni(II) complexes of bis(diphenylphosphinemethyl) aminobutyl, ((Ph2PCH2)(2)N(CH2)(3)(CH3)(3)), were synthesized using Schlenck techniques under nitrogen atmosphere. Synthesized complexes were characterized by using thermal analysis, elemental analyses, H-1 NMR, P-31 NMR, FT-IR and UV-Vis techniques. Single crystal X-Ray diffraction analysis confirms the structure of the newly synthesized compounds. The electrochemical properties of complexes were studied by using cyclic voltammetry. All complexes exhibited intra-ligand (pi ->pi*) fluorescence in CH2Cl2. Hartree Fock was used to determine the electronic structure and properties of the complexes. Band gaps of the newly synthesized complexes were calculated as 3.19eV and 3.15eV and showed good optical properties. (C) 2019 Elsevier B.V. All rights reserved.
dc.description.sponsorshipCukurova University [FDK-2014-3517, FYL-2015-5201]
dc.description.sponsorshipWe thank Cukurova University for financial support (project no. FDK-2014-3517, FYL-2015-5201). We are grateful to Sinop University, The Scientific and Technological Research Application and Research Center, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1016/j.molstruc.2019.126889
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85070262806
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.126889
dc.identifier.urihttps://hdl.handle.net/11486/6370
dc.identifier.volume1198
dc.identifier.wosWOS:000489331600066
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectBis(diphenylphosphinomethyl)aminobutyl
dc.subjectElectrochemistry
dc.subjectX-ray crystallography
dc.subjectHartree Fock
dc.subjectOptical properties
dc.titleSynthesis of phosphine-containing novel Pd(II) and Ni(II) complexes: Electrochemical, photophysical and quantum chemical studies
dc.typeArticle

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