Facile Synthesis and Crystal Structures of New Ammonium Sulfonates (CA-DNBS and TEA-TMBS)

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridAsiri, Abdullah/0000-0001-7905-3209
dc.contributor.authorKhan, Islam Ullah
dc.contributor.authorArshad, Muhammad Nadeem
dc.contributor.authorSahin, Onur
dc.contributor.authorMubashar-Ur-Rehman, Hafiz
dc.contributor.authorMunir, Ayesha
dc.contributor.authorHumayun, Saba
dc.contributor.authorAsiri, Abdullah M.
dc.date.accessioned2025-03-23T19:48:47Z
dc.date.available2025-03-23T19:48:47Z
dc.date.issued2013
dc.departmentSinop Üniversitesi
dc.description.abstractThe title compounds, C12H10N3O7SCl (I) and C15H27NO3S (II), crystallize in the monoclinic system, space group P2(1)/c with a = 7.3995(1), b = 27.8489(6), c = 9.8246(2) angstrom, beta = 131.349(1)degrees, V = 1519.82(5) angstrom(3), Z = 4, F(000) = 768, R-int = 0.033 and S = 1.03 for I, and in the orthorhombic system, space group Pbca with a = 8.6227(1), b = 16.1480(4), c = 23.8774(6) angstrom, V = 3324.67(12) angstrom(3), Z = 8, F(000) = 1312, R-int = 0.024 and S = 1.04 for II. We have devised a convenient procedure for the synthesis of fused organic salts resulting from 1:1 proton-transfer, using an amine and a derivative of benzenesulfonic acid. The synthesized salts have a number of applications ranging from their consumption as eco-friendly solvents and catalysts in organic syntheses, to being used as efficient precursors for the production of sulfa drugs. Structures of compounds 3-chloroanilinium 2,4-dinitrobenzenesulfonate (CA-DNBS) and triethylaminium 2,4,6-trimethylbenzenesulfonate (TEA-TMBS) were determined by single-crystal X-ray diffraction studies and infrared spectroscopy.
dc.identifier.endpage1474
dc.identifier.issn0254-5861
dc.identifier.issue10
dc.identifier.scopus2-s2.0-84903605069
dc.identifier.scopusqualityQ2
dc.identifier.startpage1465
dc.identifier.urihttps://hdl.handle.net/11486/7649
dc.identifier.volume32
dc.identifier.wosWOS:000326362500005
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherChinese Journal Structural Chemistry
dc.relation.ispartofChinese Journal of Structural Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectcrystal structure
dc.subjectammonium sulfonates
dc.subject3-chloroanilinium 2,4-dinitrobenzenesulfonate
dc.subjecttriethylaminium 2,4,6-trimethylbenzenesulfonate
dc.subjectionic liquids
dc.titleFacile Synthesis and Crystal Structures of New Ammonium Sulfonates (CA-DNBS and TEA-TMBS)
dc.typeArticle

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