One-dimensional coordination polymers with 4-(2-aminoethyl) pyridine: Synthesis, crystal structures and spectroscopic properties

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.contributor.authorKaraagac, Dursun
dc.contributor.authorKurkcuoglu, Giunes Suheyla
dc.contributor.authorSenyel, Mustafa
dc.contributor.authorSahin, Onur
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2025-03-23T19:38:19Z
dc.date.available2025-03-23T19:38:19Z
dc.date.issued2017
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new one-dimensional polymeric metal complexes, namely [Zn(NH3)(mu-4aepy)Ni(mu-CN)(CN)3](n) (1) and [Cu(H2O)(mu-4aepy)Pd(mu-CN)(CN)(3)](n) (2) [4aepy = 4-(2-aminoethyl)pyridine], were synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal and elemental analyses techniques. The complexes crystallize in the monoclinic system, P2(1/)n space group. The asymmetric units of 1 and 2 contain two M(II) ions [M = Zn(II) and Ni(II) in 1 and Cu(II) and Pd(II) in 2], four cyanide ligands, one 4aepy ligand and one coordinated ligand (ammine in 1 and aqua in 2) in a distorted tetragonal coordination geometry. The crystal structures of the complexes revealed that three cyanide groups are terminal whereas one different cyanide group behaves as bridging ligand. The most important features of the complexes are the presence of obvious M...pi [M(II) = Ni(II) or Pd(II)] interactions. The spectral and thermal analysis results also support the crystal structures of the complexes. (C) 2016 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipResearch Fund of Eskisehir Osmangazi Universitesi [201519047]
dc.description.sponsorshipThis paper is dedicated to Prof. Dr. Ziya KANTARCI, who died in January, 2012. The authors would like to thank the editor for considering the manuscript for review and the esteemed reviewers for reviewing and giving valuable suggestions for modifications of the paper. This work was supported by the Research Fund of Eskisehir Osmangazi Universitesi. Project number: 201519047.
dc.identifier.doi10.1016/j.poly.2016.10.046
dc.identifier.endpage61
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84998786419
dc.identifier.scopusqualityQ2
dc.identifier.startpage56
dc.identifier.urihttps://doi.org/10.1016/j.poly.2016.10.046
dc.identifier.urihttps://hdl.handle.net/11486/6125
dc.identifier.volume123
dc.identifier.wosWOS:000394063300008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCyanide complex
dc.subject1D complex
dc.subject4-(2-Aminoethyl)pyridine complex
dc.subjectCrystal structure
dc.subjectM...pi interaction
dc.titleOne-dimensional coordination polymers with 4-(2-aminoethyl) pyridine: Synthesis, crystal structures and spectroscopic properties
dc.typeArticle

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