Synthesis, characterization and crystal structures of heteronuclear coordination polymers with 4-methylpyridine

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dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.contributor.authorKekec, Seray
dc.contributor.authorKurkcuoglu, Guenes Suheyla
dc.contributor.authorSahin, Onur
dc.contributor.authorYesilel, Okan Zafer
dc.date.accessioned2025-03-23T19:44:02Z
dc.date.available2025-03-23T19:44:02Z
dc.date.issued2024
dc.departmentSinop Üniversitesi
dc.description.abstractIn this study, four new heteronuclear hexacyanoferrate(III) and hexacyanocobaltate(III) complexes, namely, [Cu2(4mpy)2Cu(4mpy)2(EtOH)2Co2(mu-CN)8(CN)4]n (1), [Zn2(4mpy)2Zn(4mpy)2Co2(mu-CN)10(CN)2]n (2), [Cd2(H2O)8Cd(4mpy)2Co2(mu-CN)8(CN)4]n (3) and [Cd3(4mpy)12Fe2(mu-CN)6(CN)6]n (4), were synthesized using 4-methylpyridine (4mpy) ligand. All complexes were investigated using single-crystal X-ray diffraction (SC-XRD), vibration (FT-IR and Raman) spectra and elemental and thermal analysis techniques. In addition, powder X-ray diffraction (PXRD) patterns were performed to verify the phase purity of the complexes. Crystallographic analyses reveal that complexes 1, 2 and 4 exhibit 2D structure while complex 3 exhibits 1D structure. Also, the 3D supramolecular structures of the complexes 1-4 formed through intermolecular C-H center dot center dot center dot N, O-H center dot center dot center dot N or O-H center dot center dot center dot O hydrogen bonding.
dc.description.sponsorshipScientific and Technological Research Application and Research Center, Sinop University, Turkey
dc.description.sponsorshipThe authors acknowledge to Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1007/s11224-023-02266-1
dc.identifier.endpage1373
dc.identifier.issn1040-0400
dc.identifier.issn1572-9001
dc.identifier.issue5
dc.identifier.scopus2-s2.0-85180706474
dc.identifier.scopusqualityQ2
dc.identifier.startpage1365
dc.identifier.urihttps://doi.org/10.1007/s11224-023-02266-1
dc.identifier.urihttps://hdl.handle.net/11486/6852
dc.identifier.volume35
dc.identifier.wosWOS:001131846400001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer/Plenum Publishers
dc.relation.ispartofStructural Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectHexacyanoferrate(III)
dc.subjectHexacyanocobaltate(III)
dc.subject4-Methylpyridine
dc.subjectCoordination polymers
dc.subjectHeteronuclear complexes
dc.titleSynthesis, characterization and crystal structures of heteronuclear coordination polymers with 4-methylpyridine
dc.typeArticle

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