One-dimensional coordination polymers of copper(II), cobalt(II), zinc(II) and cadmium(II) with glutarate and N-methylimidazole

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dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorKilic, Yalcin
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:38:21Z
dc.date.available2025-03-23T19:38:21Z
dc.date.issued2014
dc.departmentSinop Üniversitesi
dc.description.abstractFour coordination polymers, namely, {[Co(mu-glu)(nmim)(2)]center dot 2H(2)O)(n) (1), [Cu(mu-glu)(nmim)(2)] (2), [[Zn (mu-glu)(nmim)(2)]center dot 2H(2)O), (3) and [Cd(u-glu)(nmim)21 (4) (glu = glutarate, nmim = N-methylimidazole), have been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis and single-crystal X-ray diffraction techniques. Moreover, the photoluminescence properties of 3 and 4 have been investigated. Structural analyses reveal that all the complexes exhibit one-dimensional (10) linear chain structures bridged by the glutarate ligand, which further form 3D supramolecular networks via intermolecular it pi center dot center dot center dot pi, C-H center dot center dot center dot pi and weak hydrogen bonding interactions. In the complexes, the glu ligand adopts the bis-monodentate and bis-bidentate bridging modes through two and four carboxylate oxygen atoms, respectively. The distorted octahedral geometry for complexes 2 and 4 and tetrahedral geometry for complexes 1 and 3 are completed by two nmim ligands. Complexes 3 and 4 exhibit a blue emission in the solid state at room temperature. (C) 2013 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific Research Fund of Eskisehir Osmangazi University [201219002]
dc.description.sponsorshipThis work was supported by the Scientific Research Fund of Eskisehir Osmangazi University. Project number: 201219002.
dc.identifier.doi10.1016/j.poly.2013.08.068
dc.identifier.endpage128
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.scopus2-s2.0-84884624844
dc.identifier.scopusqualityQ2
dc.identifier.startpage122
dc.identifier.urihttps://doi.org/10.1016/j.poly.2013.08.068
dc.identifier.urihttps://hdl.handle.net/11486/6133
dc.identifier.volume67
dc.identifier.wosWOS:000329557200016
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCoordination polymers
dc.subjectGlutarate complex
dc.subjectN-Methylimidazole complex
dc.titleOne-dimensional coordination polymers of copper(II), cobalt(II), zinc(II) and cadmium(II) with glutarate and N-methylimidazole
dc.typeArticle

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