Spectroscopic, structural characterization and magnetic studies of Cu(II)-sulfathiazole complex with 1,10-Phenanthroline and N-(2-hydroxyethyl)-Ethylenediamine ligands

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dc.authoridAYCAN, TUGBA/0000-0002-5313-7807
dc.authoridOZTURK, FILIZ/0000-0002-0493-0446
dc.authoridCon, Ahmet Hilmi/0000-0002-1225-0133
dc.contributor.authorOzturk, Filiz
dc.contributor.authorAycan, Tugba
dc.contributor.authorCon, Ahmet Hilmi
dc.date.accessioned2025-03-23T19:39:34Z
dc.date.available2025-03-23T19:39:34Z
dc.date.issued2020
dc.departmentSinop Üniversitesi
dc.description.abstractCu(II)-sulfathiazole (Hstz:4-amino-N-(1,3-thiazol-2-yl) benzene sulfonamide) complex with phen (1,10-Phenanthroline) and Hydeten (N-(2-hydroxyethyl)-Ethylenediamine) has been synthesized and characterized by single crystal X-ray diffraction, IR, EPR and UV-Vis spectroscopy, thermal analysis. The [Cu(stz)(Hydeten)(Phen)].(stz)(Phen) complex crystallizes in the orthorhombic space group Pca2(1), Z = 4. The sulfathiazole anion acts as a monodentate ligand through the thiadiazole N atom contiguous to the deprotonated sulfonamide group. The trigonality factor (tau = (beta-alpha)/60) value of the copper complex is 0.14 and this value expresses having slightly distorted square pyramidal environment of the Cu(II) ions coordination. The powder EPR spectra of Cu(II) complex were recorded at room temperature and liquid nitrogen temperature. The EPR spectral analysis has led to that the ground state of the unpaired electron of copper ion isd(x2-y2). As results of the minimum inhibitory concentration (MIC) values obtained as results of the antimicrobial study for stz and complex, it was seen that the metal-stz complex was more effective than free stz. (C) 2019 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2019.127220
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85076106411
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.127220
dc.identifier.urihttps://hdl.handle.net/11486/6365
dc.identifier.volume1202
dc.identifier.wosWOS:000501486700084
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectX-ray crystal structure
dc.subjectSulfathiazole
dc.subjectFT-IR spectroscopy
dc.subjectEPR
dc.subjectAntimicrobial activity
dc.titleSpectroscopic, structural characterization and magnetic studies of Cu(II)-sulfathiazole complex with 1,10-Phenanthroline and N-(2-hydroxyethyl)-Ethylenediamine ligands
dc.typeArticle

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