Mn(II) and Co(II) mixed-ligand coordination compounds with acesulfame and 3-aminopyridine: synthesis and structural properties

Basit Öğe Kaydı
dc.authoridOZER, Demet/0000-0003-0862-9607
dc.contributor.authorYurdakul, Omer
dc.contributor.authorKose, Dursun Ali
dc.contributor.authorSahin, Onur
dc.contributor.authorOzer, Demet
dc.date.accessioned2025-03-23T19:35:24Z
dc.date.available2025-03-23T19:35:24Z
dc.date.issued2021
dc.departmentSinop Üniversitesi
dc.description.abstractTwo mixed ligand complexes containing acesulfame (acs) and 3-aminopyridine (3-ap) ligands of Mn(II) and Co(II) were synthesized. The obtained compounds were characterized by various analysis methods. The geometries of complexes, C18H28MnN6O12S2 (1) and C18H32CoN6O14S2 (2), are distorted octahedra. Coordination of metal cations is provided by two molecules of 3-ap and four water ligands. In both structures, the 2+ charge of the metal required two monoanionic acs molecules located outside the coordination sphere. Complex 1 contains no hydrate water, while 2 contains two molecules of hydrate water. The crystal system of 1 is monoclinic and space group P2(1)/c, while the crystal system of 2 is triclinic and space group P-1. Data on the removal of hydrate and crystalline waters in structures from thermal analysis curves support the described molecular structures. The bending vibrations of the bonds obtained from the FT-IR spectra match the crystal structure described. As a result of thermal analysis of both complexes, it was determined that the relevant metal cations remained in the reaction vessel as oxide (MnO and CoO) residues.
dc.identifier.doi10.1080/00958972.2021.1888083
dc.identifier.endpage1180
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue7
dc.identifier.scopus2-s2.0-85102252527
dc.identifier.scopusqualityQ3
dc.identifier.startpage1168
dc.identifier.urihttps://doi.org/10.1080/00958972.2021.1888083
dc.identifier.urihttps://hdl.handle.net/11486/5862
dc.identifier.volume74
dc.identifier.wosWOS:000626933900001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectAcesulfame
dc.subject3-aminopyridine
dc.subjectmetal complexes
dc.subjectcrystal structures
dc.subjectthermal analysis
dc.titleMn(II) and Co(II) mixed-ligand coordination compounds with acesulfame and 3-aminopyridine: synthesis and structural properties
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu