One-pot synthesis of two new metal-organic networks: hydrogen bonded mononuclear Cu(II) complex and mixed-valence Cu(I,II) coordination polymer with encapsulated 14-membered unique water cluster

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.contributor.authorSemerci, Fatih
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorYuksel, Fatrna
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:41:21Z
dc.date.available2025-03-23T19:41:21Z
dc.date.issued2015
dc.departmentSinop Üniversitesi
dc.description.abstract{[Cu-4(mu-bpe)(4)Cu-2(mu-pydc)(2)(mu(3)-pydc)(2)]center dot 14H(2)O}(n) (1) and [Cu(pydcH)(2)(bpe)(2)] (2) have been solvothermally synthesized by 1,2-bis(4-pyridyl)ethylene (bpe) along with dianionic pyridine-2,3-dicarboxylate (pydc) ligands and characterized by elemental, FT-IR and thermal analyses techniques. In the solvothermal synthesis of complexes, 1 was isolated when the reactor was opened whereas 2 was crystallized after 3 weeks. The X-ray crystallographic studies show that complex 1 exhibits ladder-like structure involving mixed-valence Cu(I,II) which has generated a simultaneous in situ redox reaction and a unique 14-membered water cluster consisting of an eight-membered open-cube hexamer and two cyclic water trimers has been observed in hydrophilic cavities of 1. Supramolecular network of 2, which has proton transfer product of pydcH cations, is formed by O-H center dot center dot center dot N and aromatic interactions. (C) 2015 Elsevier B.V. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [109T201]
dc.description.sponsorshipThis work has been supported by The Scientific and Technological Research Council of Turkey (TUBITAK, No: 109T201).
dc.identifier.doi10.1016/j.inoche.2015.10.016
dc.identifier.endpage33
dc.identifier.issn1387-7003
dc.identifier.issn1879-0259
dc.identifier.scopus2-s2.0-84944750633
dc.identifier.scopusqualityQ2
dc.identifier.startpage29
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2015.10.016
dc.identifier.urihttps://hdl.handle.net/11486/6563
dc.identifier.volume62
dc.identifier.wosWOS:000367123900008
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofInorganic Chemistry Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCoordination polymers
dc.subjectPyridine-2,3-dicarboxylate
dc.subject1,2-bis(4-pyridyl)ethylene
dc.subjectSolvothermal synthesis
dc.subjectWater clusters
dc.subjectMixed-valence Cu(I, II)
dc.subjectOne-pot synthesis
dc.titleOne-pot synthesis of two new metal-organic networks: hydrogen bonded mononuclear Cu(II) complex and mixed-valence Cu(I,II) coordination polymer with encapsulated 14-membered unique water cluster
dc.typeArticle

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