Two novel mixed-ligand zinc-acesulfame compounds: Synthesis, spectroscopic and thermal characterization and biological applications

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorYurdakul, Omer
dc.contributor.authorKose, Dursun Ali
dc.contributor.authorSahin, Onur
dc.contributor.authorAvci, Gulcin Alp
dc.date.accessioned2025-03-23T19:39:27Z
dc.date.available2025-03-23T19:39:27Z
dc.date.issued2020
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new tetrahedral acesulfame complexes, acesulfamato(N)acesulfamato(O)bis(3-aminopyridine) zinc(II) (C18H2ON6O8S2Zn, Zn-ace-3ap) and bis(acesulfamato-O)bis(benzotriazole)zinc(II) (C20H18N8O8S2Zn, Zn-ace-bta), were synthesized and characterized by single crystal X-ray diffraction, FT-IR spectroscopy, elemental analysis and thermal analysis techniques(TGA, DTA, DTG). The first compound, Zn-ace-3ap, crystallizes in triclinic space group P1 with parameters a = 7.978 (7) angstrom, b = 9.907 (6) angstrom, c = 15.778 (14) angstrom, alpha = 78.24 degrees (2), beta = 81.22 degrees (4), gamma = 75.99 degrees (2), Z = 2 and The second compound, Zn-ace-bta, crystallizes in monoclinic space group C2/c with parameters a = 19.879 (3) angstrom, b = 9.3637 (13) angstrom, c = 14.0852 (18) angstrom, beta = 105.483 degrees (4), Z = 4. The biological activities of the synthesized complexes were appraised through disk diffusion method as antibacterial, antimicrobial and antifungal in DMSO. Enterococcus faecalis (ATCC-29212), Staphylococcus aureus (ATCC-25923) as gram-positive bacteria, Pseudomonas aeroginosa (ATCC-27853) and Escherichia coli (ATCC-25922) as gram-negative bacteria, and Candida albicans (ATCC-10231) as fungus were grown with a view to investigate the antimicrobial effects of the complexes. (C) 2019 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2019.127265
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85075379497
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.127265
dc.identifier.urihttps://hdl.handle.net/11486/6364
dc.identifier.volume1203
dc.identifier.wosWOS:000504448700003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectAcesulfame
dc.subjectBenzotriazole
dc.subjectBiological applications
dc.subject3-Aminopyridine
dc.titleTwo novel mixed-ligand zinc-acesulfame compounds: Synthesis, spectroscopic and thermal characterization and biological applications
dc.typeArticle

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