Molecular Structure and Supramolecular Architecture of (E)-2-Bromo-6-[(2,4,6-Tribromophenylimino)methyl]-4-Chlorophenol

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dc.authoridAlbayrak kastas, Cigdem/0000-0003-0235-7460
dc.authoridERSANLI, CEM CUNEYT/0000-0002-8113-5091
dc.contributor.authorAlbayrak Kastas, C.
dc.contributor.authorKastas, G.
dc.contributor.authorKirca, B. Kosar
dc.contributor.authorErsanli, C. C.
dc.date.accessioned2025-03-23T19:31:39Z
dc.date.available2025-03-23T19:31:39Z
dc.date.issued2020
dc.departmentSinop Üniversitesi
dc.description.abstractIn this study, the molecular structure and supramolecular architecture of a new compound have been studied in depth using single crystal X-ray diffraction (XRD) technique. Crystallographic results show that the compound exists in phenol-imine form that is twisted with the dihedral angle of 51.77 degrees between the aromatic rings of the molecule. Various types of non-covalent interactions (C...O, C-H...O, Br...Br, C-H...Cl, pi...pi, O...Br, and Br...pi) take part effectively in the construction of 3D network in the compound. The C...O and C-H...O interactions have the role of forming the 1D structure along the direction [010] with the support of pi...pi and pi...Br interactions. The 2D structure of the compound is reached by the inter-connection of 1D chains in the (101) plane through the C-H...Cl interactions. The 3D supramolecular structure of the compound is completed by the non-covalent Br...Br and Br...O interactions responsible for the connection of 2D sheets.
dc.description.sponsorshipSinop University Scientific Research Coordination Unit [FEF-1901-13-07]
dc.description.sponsorshipThis work was supported by Sinop University Scientific Research Coordination Unit. Project no. FEF-1901-13-07. The authors acknowledge to Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1134/S1063774520070093
dc.identifier.endpage1110
dc.identifier.issn1063-7745
dc.identifier.issn1562-689X
dc.identifier.issue7
dc.identifier.scopus2-s2.0-85096512019
dc.identifier.scopusqualityQ4
dc.identifier.startpage1106
dc.identifier.urihttps://doi.org/10.1134/S1063774520070093
dc.identifier.urihttps://hdl.handle.net/11486/5327
dc.identifier.volume65
dc.identifier.wosWOS:000592546300002
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPleiades Publishing Inc
dc.relation.ispartofCrystallography Reports
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCenter-Dot-Cl
dc.subjectSolid-State
dc.subjectTautomerism
dc.subjectCrystal
dc.titleMolecular Structure and Supramolecular Architecture of (E)-2-Bromo-6-[(2,4,6-Tribromophenylimino)methyl]-4-Chlorophenol
dc.typeArticle

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