Dichlorotriethylphosphine-[N-formyl-N,N'-bis(3,4-dimethoxy)benzyl-trimethylenediamine] platinum(II)

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dc.authoridKARACA, EMINE OZGE/0000-0003-2094-9742
dc.authoridyasar, sedat/0000-0001-7285-2761
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.contributor.authorSahin, O.
dc.contributor.authorOzcan, E. O.
dc.contributor.authorGurbuz, N.
dc.contributor.authorOzdemir, I.
dc.contributor.authorBuyukgungor, O.
dc.date.accessioned2025-03-23T19:31:43Z
dc.date.available2025-03-23T19:31:43Z
dc.date.issued2014
dc.departmentSinop Üniversitesi
dc.description.abstractBy treatment of 1,3-bis(3,4-dimethoxybenzyl)-3,4,5,6-tetrahydropyrimidinium chloride (1) with KOBu (t) and [PtCl2(PEt3)(2)](2) N-coordinated platinum complex (2) is obtained. The Pt atom is coordinated in square planar arrangements by two chloride ions in a trans-configuration, the N-formyl-N,N'-bisaryltrimethylenediamine nitrogen atom, and the phosphine P atom. An extensive three-dimensional network of three C-HaEuro broken vertical bar O hydrogen bonds, two C-HaEuro broken vertical bar pi and one pi aEuro broken vertical bar pi interactions are responsible for the crystal stabilization. Intermolecular hydrogen bonds and C-HaEuro broken vertical bar pi interactions produce R (2) (2) (6), R (2) (2) (22), R (2) (2) (24), R (3) (3) (23), R (4) (4) (26), and R (4) (4) (32) rings.
dc.identifier.doi10.1134/S0022476614040155
dc.identifier.endpage702
dc.identifier.issn0022-4766
dc.identifier.issn1573-8779
dc.identifier.issue4
dc.identifier.scopus2-s2.0-84919352182
dc.identifier.scopusqualityQ3
dc.identifier.startpage697
dc.identifier.urihttps://doi.org/10.1134/S0022476614040155
dc.identifier.urihttps://hdl.handle.net/11486/5345
dc.identifier.volume55
dc.identifier.wosWOS:000342415000015
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPleiades Publishing Inc
dc.relation.ispartofJournal of Structural Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjecttetrahydropyrimidine
dc.subjectN-formyl-N,N'-bisaryltrimethylenediamine
dc.subjectPt(II) complex
dc.subjectX-ray diffraction analysis
dc.titleDichlorotriethylphosphine-[N-formyl-N,N'-bis(3,4-dimethoxy)benzyl-trimethylenediamine] platinum(II)
dc.typeArticle

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