Synthesis, spectroscopic, structural characterizations, and catalytic properties of cyanide-bridged heteronuclear metal organic frameworks with imidazole

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dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.authoridMwanza, Telvin/0000-0001-8155-626X
dc.contributor.authorMwanza, Telvin
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorUnver, Hakan
dc.contributor.authorSahin, Onur
dc.contributor.authorYesilel, Okan Zafer
dc.date.accessioned2025-03-23T19:40:57Z
dc.date.available2025-03-23T19:40:57Z
dc.date.issued2022
dc.departmentSinop Üniversitesi
dc.description.abstractThree new cyanide-bridged metal complexes of the general formula [Cu-2(mu-im)(2)(im)(4)M(mu-CN)(4)] n (where M = Ni(II) for 1, Pd(II) for 2, and Pt(II) for 3; im: imidazole) have been synthesized. All 1-3 were investigated using different and properly chosen physicochemical methods: Fourier transform infrared (FT-IR) and Raman spectroscopies (R), thermal analysis (TG, DTG, DTA), powder and single-crystal X-ray diffraction (PXRD and SC-XRD). The polymeric structures of all complexes crystalize in the same triclinic P-1 space group. Brunauer-Emmett-Teller (BET) method was used for the surface area analysis. The average particle size and morphology were estimated by scanning and transmission electron microscope (SEM and TEM). The heterogeneous catalytic activity of complex 2 catalysts was evaluated on the Suzuki-Miyaura reaction between selected aryl halides and phenyboronic acid. Complex 2 exhibits moderate to high heterogeneous catalyst activity for the Suzuki C-C coupling reaction in an organic/water solvent environment.
dc.description.sponsorshipEskisehir Osmangazi University, Scientific research Unit [201919018]
dc.description.sponsorshipThis work has been financially supported by Eskisehir Osmangazi University, Scientific research Unit (Grant No: 201919018).
dc.identifier.doi10.1016/j.jssc.2022.123344
dc.identifier.issn0022-4596
dc.identifier.issn1095-726X
dc.identifier.scopus2-s2.0-85132916199
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.jssc.2022.123344
dc.identifier.urihttps://hdl.handle.net/11486/6472
dc.identifier.volume314
dc.identifier.wosWOS:000861560700006
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAcademic Press Inc Elsevier Science
dc.relation.ispartofJournal of Solid State Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectHeteronuclear complexes
dc.subjectTetracyanonickelate(II) complex
dc.subjectTetracyanopalladate(II) complex
dc.subjectTetracyanoplatinate(II) complex
dc.subjectImidazole complex
dc.subjectSuzuki-Miyaura
dc.titleSynthesis, spectroscopic, structural characterizations, and catalytic properties of cyanide-bridged heteronuclear metal organic frameworks with imidazole
dc.typeArticle

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