Heteronuclear Hexacyanometallate(III) Coordination Polymers (Cd/Cr, Cd/Fe, Cd/Co) with 3-(Aminomethyl)pyridine: Synthesis, Characterization, and Catalytic Activities for the Peroxidative Oxidation of Benzylic Alcohols

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dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.contributor.authorKekec, Seray
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorUnver, Hakan
dc.contributor.authorSahin, Onur
dc.contributor.authorYesilel, Okan Zafer
dc.date.accessioned2025-03-23T19:44:13Z
dc.date.available2025-03-23T19:44:13Z
dc.date.issued2024
dc.departmentSinop Üniversitesi
dc.description.abstractThree new heteronuclear hexacyanometallate(III) coordination polymers (CPs), [Cd3(mu-3ampy)4(H2O)4Cr2(mu-CN)8(CN)4]n (1), [Cd3(mu-3ampy)2(H2O)2Fe2(mu-CN)5(CN)7]n (2) and [Cd3(mu-3ampy)4(H2O)4Co2(mu-CN)8(CN)4]n (3), were synthesized with 3-(aminomethyl)pyridine (3ampy) ligand. All CPs were characterized by FT-IR, Raman, elemental, thermal analysis as well as single crystal X-ray diffraction and powder X-ray diffraction techniques. The single crystal X-ray diffraction analyses shows that the CPs 1 and 3 are two-dimensional structures, whereas CP 2 is a three-dimensional structure where two adjacent metal ions ions are linked via 3ampy and CN bridges. The coordination spheres of all CPs show distorted octahedral geometries. CP 3 was mainly tested as heterogenous catalyst for peroxidative oxidation of benzyl alcohol and its derivatives (4-chloro, 4-bromo, 4-methyl, 4-metoxy and 4-nitro benzyl alcohol). From the results, the highest aldehyde formation was obtained from the oxidation of benzyl alcohol with overall yield as 100%. In addition, catalytic reactions exhibited high selectivity towards aldehyde and no over-oxidation product (carboxylic acid) was observed.
dc.description.sponsorshipEskisehir Osmangazi University, Scientific research Unit [2022-2561]
dc.description.sponsorshipThis work has been financially supported by Eskisehir Osmangazi University, Scientific research Unit [Grant No: 2022-2561].
dc.identifier.doi10.1007/s10904-023-02861-z
dc.identifier.endpage1091
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue3
dc.identifier.scopus2-s2.0-85173957509
dc.identifier.scopusqualityQ1
dc.identifier.startpage1081
dc.identifier.urihttps://doi.org/10.1007/s10904-023-02861-z
dc.identifier.urihttps://hdl.handle.net/11486/6902
dc.identifier.volume34
dc.identifier.wosWOS:001077523700002
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectHexacyanochromate(III)
dc.subjectHexacyanoferrate(III)
dc.subjectHexacyanocobaltate(III)
dc.subject3-(Aminomethyl)pyridine complex
dc.subjectCoordination polymer
dc.subject2D complex
dc.subject3D complex
dc.subjectCatalyst
dc.titleHeteronuclear Hexacyanometallate(III) Coordination Polymers (Cd/Cr, Cd/Fe, Cd/Co) with 3-(Aminomethyl)pyridine: Synthesis, Characterization, and Catalytic Activities for the Peroxidative Oxidation of Benzylic Alcohols
dc.typeArticle

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