A disparate 3-D silver(I) coordination polymer of pyridine-3,5-dicarboxylate and pyrimidine with strong intermetallic interactions: X-ray crystallography, photoluminescence and antimicrobial activity

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dc.authoridHamamci Alisir, Sevim/0000-0001-7296-8318
dc.contributor.authorAlisir, Sevim Hamamci
dc.contributor.authorDemir, Serkan
dc.contributor.authorSariboga, Bahtiyar
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:35:26Z
dc.date.available2025-03-23T19:35:26Z
dc.date.issued2015
dc.departmentSinop Üniversitesi
dc.description.abstractA polymeric silver(I) complex, [Ag-4(-pydc)(2)(-pm)(2)](n) (1) (pydc=pyridine-3,5-dicarboxylate and pm=pyrimidine), has been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis, and single-crystal X-ray diffraction. X-ray crystallographic data of 1 revealed that pydc exhibits two different coordinaton modes that play a key role in the construction of the 3-D crystal network including Ag-carboxylate clusters in which close Ag-Ag distances exist. The magnitudes of close Ag-Ag interactions in second-order energy (E-2) have been revealed by natural bond orbital analysis performed with single point energy calculation using the experimental geometry of 1. Furthermore, the luminescent properties of 1 show strong fluorescence with two emission maxima in the visible region. Also, 1 has antifungal activity on Candida albicans (MIC value, 4gmL(-1)) and good antibacterial activity on micro-organisms (MIC value, 64-256gmL(-1)).
dc.description.sponsorshipResearch Fund of Ondokuz Mayis University [PYO.MUH.1901.11.011]; Sinop University
dc.description.sponsorshipThe authors are grateful to the Research Fund of Ondokuz Mayis University (Project No. PYO.MUH.1901.11.011) and Sinop University for financial support of this work. We also thank Assoc. Prof Okan Zafer Yesilel for his assistance and Fatih Semerci in obtaining the luminescence spectra.
dc.identifier.doi10.1080/00958972.2014.978307
dc.identifier.endpage168
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue1
dc.identifier.scopus2-s2.0-84941733247
dc.identifier.scopusqualityQ3
dc.identifier.startpage155
dc.identifier.urihttps://doi.org/10.1080/00958972.2014.978307
dc.identifier.urihttps://hdl.handle.net/11486/5870
dc.identifier.volume68
dc.identifier.wosWOS:000346266500012
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectSilver(I) complex
dc.subjectPyridine-3
dc.subject5-dicarboxylate
dc.subjectCoordination polymer
dc.subjectPhotoluminescent properties
dc.subjectAntimicrobial properties
dc.titleA disparate 3-D silver(I) coordination polymer of pyridine-3,5-dicarboxylate and pyrimidine with strong intermetallic interactions: X-ray crystallography, photoluminescence and antimicrobial activity
dc.typeArticle

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