Investigation of structural analysis and thermostatic properties of thermal and UV stabilizer as organometallic Sn(II), Cu(II) and Cd(II) barbiturate complexes

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.contributor.authorKavlak, Ilkan
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:39:36Z
dc.date.available2025-03-23T19:39:36Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractIn this study, five new organometallic barbiturate complexes which are described in Cu(C4H3-N2O3)(2)center dot 2H(2)O (1), Cd(C4H3N2O3)(2)center dot 4H(2)O (2), Sn(C4H3N2O3)(4)center dot 4H(2)O (3), Sn(C4H3N2O3)(2)center dot Ni(B4O7)center dot 4H(2)O (4), Sn(C4H3N2O3)(2)center dot Cu(B4O7)center dot 3H(2)O (5) have been synthesized. Their contribution to the thermal and UV stabilization of PVC was investigated by thermostatic analysis via according to ISO 182-2 standard. Additionally, the structural properties of the synthesized complexes were investigated by elemental analysis, powder XRD and vibrational (FT-IR and Raman) spectroscopic techniques. Furthermore, complex 1 has been investigated by single crystal X-ray diffraction technique. The results are shown that synthesized complexes act as HCl scavengers during the PVC decomposition. The thermal decay of PVC dough, which is including in new generation plastic additives, are following: 1 > 3> 5 > 2>4. (C) 2019 Elsevier B.V. All rights reserved.
dc.description.sponsorshipEskisehir Osmangazi University, Scientific research Unit [2017-1588]
dc.description.sponsorshipThe authors are highly thankful to the Eskisehir Osmangazi University, Scientific research Unit (Project No. 2017-1588). The authors acknowledge Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1016/j.molstruc.2019.02.017
dc.identifier.endpage426
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85062212411
dc.identifier.scopusqualityQ1
dc.identifier.startpage418
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.02.017
dc.identifier.urihttps://hdl.handle.net/11486/6376
dc.identifier.volume1184
dc.identifier.wosWOS:000461047100047
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectPVC
dc.subjectThermal stabilizer
dc.subjectOrganometallic complex
dc.subjectENISO-182-2
dc.subjectDehydrochlorination
dc.subjectHCl scavengers
dc.titleInvestigation of structural analysis and thermostatic properties of thermal and UV stabilizer as organometallic Sn(II), Cu(II) and Cd(II) barbiturate complexes
dc.typeArticle

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