One- and three-dimensional silver(I)-5-sulfosalicylate coordination polymers having ligand-supported and unsupported argentophilic interactions

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dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.authoridArici, Mursel/0000-0001-8527-1587
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorArici, Mursel
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorYesiloz, Yesim
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:40:58Z
dc.date.available2025-03-23T19:40:58Z
dc.date.issued2014
dc.departmentSinop Üniversitesi
dc.description.abstractFour new coordination polymers, namely, {Hemim center dot[Ag(Hssa)(H2O)]}(n) (1), {[Ag(ina)(2) Ag(Hssa)]center dot CH3OH center dot H2O}(n) (2)center dot{[Ag-2(Hssa)(dmP)(1.5)]center dot 2H(2)O}(n) (3) and [Ag-2(Hssa)(daoc)](n) (4) (Hssa: 5-Sulfosalicylate, emim: 2-ethyl-4-methylimidazole, ina: isonicotinamide, dmp: 2,5-dimethylpyrazine and daoc: 1,8-diaminooctane) were synthesized and characterized by IR spectroscopy, elemental analysis, single crystal X-ray diffraction, powder X-ray diffraction (PXRD) and thermal analysis techniques. Complexes 1 and 2 are one-dimensional (1D) coordination polymers while complexes 3 and 4 are threedimensional (3D) coordination polymers. Complex 3 consists of three dimensional (3D) 3,3,6-c net with 3,3,6T37 topology. Complex 4 exhibits a 2-fold interpenetrating 3D framework with tfc topology. Complexes 1-4 contain ligand-supported (1-3) and unsupported (4) argentophilic Ag center dot center dot center dot Ag interactions. Photoluminescence spectra of the complexes demonstrate that photoluminescent properties may be attributed to intraligand transition of coordinated Hssa ligand. (C) 2014 Elsevier Inc. All rights reserved.
dc.identifier.doi10.1016/j.jssc.2014.08.009
dc.identifier.endpage78
dc.identifier.issn0022-4596
dc.identifier.issn1095-726X
dc.identifier.scopus2-s2.0-84906833156
dc.identifier.scopusqualityQ1
dc.identifier.startpage70
dc.identifier.urihttps://doi.org/10.1016/j.jssc.2014.08.009
dc.identifier.urihttps://hdl.handle.net/11486/6475
dc.identifier.volume220
dc.identifier.wosWOS:000343346100011
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAcademic Press Inc Elsevier Science
dc.relation.ispartofJournal of Solid State Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectSilver(I) complex
dc.subject5-Sulfosalicylate complexes
dc.subjectArgentophilic interactions
dc.subject1D and 3D coordination polymers
dc.titleOne- and three-dimensional silver(I)-5-sulfosalicylate coordination polymers having ligand-supported and unsupported argentophilic interactions
dc.typeArticle

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