Facile solvothermal syntheses of isostructural lanthanide(III) formates: Photocatalytic, photoluminescent chemosensing properties, and proficient precursors for metal oxide nanoparticles

Basit Öğe Kaydı
dc.contributor.authorFarid, Sidra
dc.contributor.authorAmeen, Saima
dc.contributor.authorSharif, Shahzad
dc.contributor.authorTariq, Madiha
dc.contributor.authorKundi, Israr Ahmad
dc.contributor.authorSahin, Onur
dc.contributor.authorSayyad, Muhammd Hassan
dc.date.accessioned2025-03-23T19:35:24Z
dc.date.available2025-03-23T19:35:24Z
dc.date.issued2021
dc.departmentSinop Üniversitesi
dc.description.abstractThree isostructural lanthanide coordination polymers (CPs) with the formula C(3)H(3)LnO(6) [Ln = Pr (1), Ce (2), and Dy (3)] were solvothermally synthesized by self-assembly of lanthanide(III) and in-situ generated methanoic acid by the hydrolysis of N,N-dimethyl formamide. These CPs were characterized by FTIR, elemental analysis, PXRD, and single crystal analysis. The metal centered luminescence properties of these coordination polymers revealed that only the dysprosium based CP exhibited significant luminescence, and it was found to be selective for chemosensing of picric acid. 3 showed quenching efficiency of 89.7% with K-SV value of 2.89 x 10(4) M-1. These coordination polymers were also exploited as photocatalysts for degradation of methylene blue, and the dysprosium based CP proved to be a fantastic photocatalyst with the degradation activity of 92% owing to its effective electronic transitions. The solvent-free thermolysis of these LnCPs fabricated CeO2 and Pr6O11 nanoparticles characterized by PXRD, FTIR, particle size analyzer, and elemental analysis.
dc.description.sponsorshipHigher Education Commission of Pakistan, HEC project [01-ISULL/09/GCUL/ACAD/HEC/2017/166]; Office of Research Innovation & Commercialization GC University, Lahore, ORIC project [108/ORIC/19]
dc.description.sponsorshipWe gratefully acknowledge financial assistance from the Higher Education Commission of Pakistan, HEC project no. 01-ISULL/09/GCUL/ACAD/HEC/2017/166 and Office of Research Innovation & Commercialization GC University, Lahore, ORIC project no. 108/ORIC/19.
dc.identifier.doi10.1080/00958972.2021.1907843
dc.identifier.endpage1719
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue9-10
dc.identifier.scopus2-s2.0-85104283734
dc.identifier.scopusqualityQ3
dc.identifier.startpage1700
dc.identifier.urihttps://doi.org/10.1080/00958972.2021.1907843
dc.identifier.urihttps://hdl.handle.net/11486/5861
dc.identifier.volume74
dc.identifier.wosWOS:000639686900001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectLanthanide formats
dc.subjectluminescence
dc.subjectchemosensing
dc.subjectphotocatalyst
dc.subjectnanoparticles
dc.titleFacile solvothermal syntheses of isostructural lanthanide(III) formates: Photocatalytic, photoluminescent chemosensing properties, and proficient precursors for metal oxide nanoparticles
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu