Synthesis and characterization of Cu(II) complexes of pyrazine-2,3-dicarboxylicacid

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dc.authoridANDAC, Omer/0000-0003-3641-9690
dc.authoridYalcin, Bahattin/0000-0003-4448-1101
dc.contributor.authorTascioglu, Sulin
dc.contributor.authorAydin, Adnan
dc.contributor.authorYalcin, Bahattin
dc.contributor.authorKaki, Esra
dc.contributor.authorAndac, Omer
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorKosar, Basak
dc.date.accessioned2025-03-23T19:38:22Z
dc.date.available2025-03-23T19:38:22Z
dc.date.issued2011
dc.departmentSinop Üniversitesi
dc.description.abstractFour copper(II) coordination polymers, {[Cu(pz(COO)(2))(H2O)](4)center dot HBr}(n) (1). {[Cu(pz(COO)(2))(NH3)(2)]center dot H2O}(n) (2), {[Cu3H2(pz(COO)(2))(4)(H2O)(3)]center dot 2H(2)O}(n) (3) and {[Cu-2(pz(COO)(2))(2)(NH3)(2)(H2O)(3)][Cu(pz(COO)(2))(NH3) (H2O)(2)][Cu(pz(COO)(2))(NH3)(H2O)]center dot 2H(2)O}(n) (4) were synthesized using pyrazine-2,3-dicarboxylic acid, CuBr2, 2-(2-aminoethylamino)ethanol/triethanol amine/ammonia in a methanol:water (1:1) solution, and the mixed ligand complexes were characterized by spectroscopic methods, thermal and elemental analysis, and magnetic susceptibility. Complexes 2 and 4 were also characterized by means of single crystal X-ray crystallography. The characterizations show that the complexes have polynuclear molecular structures, except for complex 2, and all of the complex structures form polymeric chains. Complex 4 has a pseudo-merohedral twin structure. (C) 2011 Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.poly.2011.05.018
dc.identifier.endpage2180
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.issue13
dc.identifier.scopus2-s2.0-79961017212
dc.identifier.scopusqualityQ2
dc.identifier.startpage2171
dc.identifier.urihttps://doi.org/10.1016/j.poly.2011.05.018
dc.identifier.urihttps://hdl.handle.net/11486/6134
dc.identifier.volume30
dc.identifier.wosWOS:000294572900001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectPyrazine-2,3-dicarboxylic acid
dc.subjectCopper(II) bromide complexes
dc.subjectCopper(II) mixed ligand complexes
dc.subjectTwin structure
dc.titleSynthesis and characterization of Cu(II) complexes of pyrazine-2,3-dicarboxylicacid
dc.typeArticle

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