Synthesis, characterization, electrical conductivity and luminescence properties of two copper(II) complexes with tridentate N2O chelating ligands containing imine bond

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dc.authoridgonul, ilyas/0000-0002-7697-3613
dc.contributor.authorGonul, Ilyas
dc.contributor.authorAy, Burak
dc.contributor.authorKaraca, Serkan
dc.contributor.authorSahin, Onur
dc.contributor.authorSerin, Selahattin
dc.date.accessioned2025-03-23T19:39:37Z
dc.date.available2025-03-23T19:39:37Z
dc.date.issued2018
dc.departmentSinop Üniversitesi
dc.description.abstractIn the present study, we describe the synthesis and characterization of two tridentate N2O donor ligands, namely, (E)-2-(((2-(diethylamino)ethyl)imino)methyl)-6-methoxyphenol (HL1) and (E)-2-(((2-(diethylamino)ethyl)imino)methyl)-6-ethoxyphenol (HL2), and their copper(II) complexes, [Cu(L-1)(CH3COO)] (1), [Cu(L-2)(CH3COO)] (2). They have been synthesized under conventional methods and characterized by elemental analysis, FTIR, H-1 and C-13 NMR, ICP-OES, TGA and GC/MS analysis. For the morphological analysis field emission scanning electron microscopy (FESEM) was used. The geometry of the copper(II) complexes was determined by single crystal X-ray diffraction analysis. The copper(II) ions are in distorted square-pyramidal coordination environments. Complexes crystallize in monoclinic space group, P2(1)/c. The electrical conductivity and luminescence properties of 1-2 have been investigated. (C) 2017 Elsevier B.V. All rights reserved.
dc.description.sponsorshipResearch Unit of Cukurova University, Turkey [FBA-2017-7794]; Scientific and Technological Research Application and Research Center, Sinop University, Turkey
dc.description.sponsorshipThe authors gratefully acknowledge financial support from the Research Unit of Cukurova University (Grant No. FBA-2017-7794), and Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1016/j.molstruc.2017.12.020
dc.identifier.endpage472
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85037524592
dc.identifier.scopusqualityQ1
dc.identifier.startpage465
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.12.020
dc.identifier.urihttps://hdl.handle.net/11486/6389
dc.identifier.volume1156
dc.identifier.wosWOS:000425075900055
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectSoluble Schiff base metal complexes
dc.subjectCopper (II) complexes
dc.subjectLuminescence
dc.subjectElectrical conductivity
dc.subjectSingle crystal X-ray
dc.titleSynthesis, characterization, electrical conductivity and luminescence properties of two copper(II) complexes with tridentate N2O chelating ligands containing imine bond
dc.typeArticle

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