(E)-4-Methoxy-2-(o-tolyliminomethyl)phenol
Yükleniyor...
Tarih
2009
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Acta Crystallographica Section E
Erişim Hakkı
Özet
In the molecule of the title compound, C15H15NO2, the aromatic rings are oriented at a dihedral angle of 15.46 (6)°. An intramolecular O-H...N hydrogen bond results in the formation of a nearly planar six-membered ring [maximum deviation of 0.035 (5) Å for the N atom] which is almost coplanar with the adjacent ring, making a dihedral angle of 0.8 (3)°. The title organic molecule is a phenol-imine tautomer, as evidenced by the C-O, C-N and C-C bond lengths. Molecules are linked by intermolecular C-H...O hydrogen bonds that generate a C(5) chain. C-H...[pi] and [pi]-[pi] interactions exist in the structure. The [pi]-[pi] interaction occurs between the phenol ring and its symmetry equivalent at (1 - x, 1 - y, -z), with a centroid-centroid distance of 3.727 (7) Å and a plane-to-plane separation of 3.383 (5) Å, resulting in an offset angle of 24.82 (1)°.
Açıklama
Anahtar Kelimeler
Single-crystal X-ray study
Kaynak
WoS Q Değeri
Scopus Q Değeri
Cilt
Sayı
Künye
Özek, A., Büyükgüngör, O., Albayrak, Ç., Odabaşoğlu, M. "(E)-4-Methoxy-2-(o-tolyliminomethyl)phenol". Acta Crystallographica Section E, (2009). E65, o791.
