Two dimensional coordination polymers with 3,3′-thiodipropionate: An unprecedented coordination mode and strong hydrogen-bond network

Basit Öğe Kaydı
dc.authoridArici, Mursel/0000-0001-8527-1587
dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorArici, Mursel
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:38:21Z
dc.date.available2025-03-23T19:38:21Z
dc.date.issued2014
dc.departmentSinop Üniversitesi
dc.description.abstractFour novel coordination polymers, namely [Co(mu(3)-tdp)(ina)(2)](n) (1), [Cu(mu(3)-tdp)(ina)(2)](n) (2), [Zn(mu(3)-tdp)(ina)(2)] (3) and [Zn(mu(3)-tdp)(na)2](n) (4) [tdp: 3,3'-thiodipropionate, ma: isonicotinamide and na: nicotinamide], were synthesized and structurally characterized by elemental analysis, IR and single-crystal X-ray diffraction techniques. Each M(II) ion (M(II)=Co(II) in I, Cu(II) in 2, Zn(II) in 3 and Zn(II) in 4) is coordinated by two nitrogen atoms of two different pyridine rings and four oxygen atoms from three different tdp ligands, forming distorted octahedral geometries. The tdp ligand exhibits an unprecedented coordination mode, namely the mu(3)-kappa O,O':kappa O:kappa O-bridging mode. Single crystal X-ray diffraction analysis results demonstrated that complexes 1-4 exhibit 2D layers with a point symbol of 3(3)center dot 4(3)center dot 5(4), which are extended into 3D supramolecular frameworks by R-2(2)(8) hydrogen-bonding motifs. Thermal analysis results showed that 2D complexes are stable up to 225, 189, 196 and 162 C, respectively. Moreover, the photoluminescent properties of complexes 3 and 4 were investigated at room temperature. (C) 2013 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific Research Fund of Eskiehir Osmangazi University [201219A101]
dc.description.sponsorshipThis work was supported by the Scientific Research Fund of Eskiehir Osmangazi University. Project number: 201219A101.
dc.identifier.doi10.1016/j.poly.2013.09.040
dc.identifier.endpage463
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84886178926
dc.identifier.scopusqualityQ2
dc.identifier.startpage456
dc.identifier.urihttps://doi.org/10.1016/j.poly.2013.09.040
dc.identifier.urihttps://hdl.handle.net/11486/6132
dc.identifier.volume67
dc.identifier.wosWOS:000329557200057
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subject3,3'-Thiodipropionate complex
dc.subject3,3'-Thiodipropionic acid
dc.subjectTwo-dimensional complex
dc.subjectIsonicotinamide complex
dc.subjectNicotinamide complex
dc.titleTwo dimensional coordination polymers with 3,3′-thiodipropionate: An unprecedented coordination mode and strong hydrogen-bond network
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu