1D heteronuclear coordination polymers of hexacyanocobaltate(III) with 2-hydroxymethylpyridine

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dc.contributor.authorKekec, Seray
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:38:17Z
dc.date.available2025-03-23T19:38:17Z
dc.date.issued2024
dc.departmentSinop Üniversitesi
dc.description.abstractThree new hexacyanocobaltate(III) complexes, {[M 2 (hmpy) 4 Co( mu- CN) 4 (CN) 2 ] center dot 2H 2 O} n (M = Cu(II) ( 1 ), Zn(II) ( 2 ) and Cd(II) ( 3 )) were synthesized with 2-hydroxymethylpyridine (hmpy) ligand, and characterized by vibration (FT - IR and Raman) spectral, single crystal X-ray diffraction (SC-XRD) and powder X-ray diffraction (PXRD), thermal and elemental analyses techniques. The crystallographic analyses revealed that cyanide complexes 1 - 3 are infinite one-dimensional coordination polymers. Each M ion is coordinated by two nitrogen and two oxygen atoms from the hmpy ligands and two nitrogen atoms from the cyanide ligands, displaying a distorted octahedral coordination geometry. Similarly, each Co(III) ion is coordinated by six carbon atoms from cyanide ligands to form a distorted octahedral coordination geometry. These complexes form 3D supramolecular networks through O - H & sdot;& sdot;& sdot; O hydrogen bonds and C - H & sdot;& sdot;& sdot; N interactions. Additionally, structural analyses such as metal salts, pH values of the compounds obtained under different conditions were evaluated. A synthesis -structural analyses relation was made from these data.
dc.identifier.doi10.1016/j.poly.2024.117096
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.scopus2-s2.0-85195800338
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.poly.2024.117096
dc.identifier.urihttps://hdl.handle.net/11486/6116
dc.identifier.volume260
dc.identifier.wosWOS:001255178500001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectHexacyanocobaltate(III)
dc.subject1D coordination polymer
dc.subject2-(hydroxymethyl)pyridine complexes
dc.subjectCyanide complexes
dc.title1D heteronuclear coordination polymers of hexacyanocobaltate(III) with 2-hydroxymethylpyridine
dc.typeArticle

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