Dinuclear zinc(II) complex with tris(2-aminoethyl) amine ligand: synthesis, structure and properties

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dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorSahin, Onur
dc.contributor.authorSayin, Elvan
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:30:12Z
dc.date.available2025-03-23T19:30:12Z
dc.date.issued2015
dc.departmentSinop Üniversitesi
dc.description.abstractThe dinuclear complex tris(2-aminoethyl) aminezinc(II)-mu-cyanothreecyanozincate(II) hemihydrate, [Zn(tren) Zn(mu-CN)(CN)(3)]center dot 0.5H(2)O (1) (tren = tris(2-aminoethyl)amine), has been synthesized and characterized by spectral (FT-IR and Raman), elemental, thermal analysis (TG, DTG and DTA) as well as single crystal X-ray diffraction techniques. The asymmetric unit is composed of two Zn(II) ions, one tren ligand, four cyanide ligands and a half crystal water molecule which is situated at the special position. Zn1 ion exhibits tetrahedral coordination geometry with four carbon atoms of four cyanide ligands. Zn2 ion is five-coordinated by five nitrogen atoms from one tren and one cyanide ligands in a trigonal bipyramid coordination geometry. The cyanide nitrogen is in the axial position. Adjacent dinuclear units are connected by hydrogen bonding interactions to form three dimensional network. The decomposition reaction takes place in the temperature range 30-700 degrees C in the static air atmosphere.
dc.identifier.doi10.1515/zkri-2014-1814
dc.identifier.endpage412
dc.identifier.issn2194-4946
dc.identifier.issn2196-7105
dc.identifier.issue6
dc.identifier.scopus2-s2.0-84941342092
dc.identifier.scopusqualityQ3
dc.identifier.startpage407
dc.identifier.urihttps://doi.org/10.1515/zkri-2014-1814
dc.identifier.urihttps://hdl.handle.net/11486/5041
dc.identifier.volume230
dc.identifier.wosWOS:000355199900004
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWalter De Gruyter Gmbh
dc.relation.ispartofZeitschrift Fur Kristallographie-Crystalline Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectcyanide complex
dc.subjectdinuclear complex
dc.subjecttetracyanozincate(II)
dc.subjecttris(2-aminoethyl)amine
dc.subjectzinc(II) complex
dc.titleDinuclear zinc(II) complex with tris(2-aminoethyl) amine ligand: synthesis, structure and properties
dc.typeArticle

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