One-Pot hydrothermal synthesis of 1D copper (II) coordination polymers involving in-situ decarboxylation

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dc.authoridAY, BURAK/0000-0001-7055-8139
dc.contributor.authorAy, Burak
dc.contributor.authorSahin, Onur
dc.contributor.authorYildiz, Emel
dc.date.accessioned2025-03-23T19:37:51Z
dc.date.available2025-03-23T19:37:51Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractOne-Dimensional Copper(II) coordination polymers with the formula [Cu(2-pyc)(2)](n)center dot nH(2)O (1) (2-Hpyc: Picolinic acid) and [Cu(1,10-phen)(SO4)(H2O)(2)](n) (2) (1,10-phen: 1,10-phenanthroline) have been co-synthesized under hydrothermal conditions in the same medium. The coordination polymers characterized by elemental analysis, FT-IR spectroscopy, TG analysis, ICP-OES, PXRD and single crystal X-ray diffraction. The compound 1 crystallizes in triclinic system, space group P-1, the compound 2 crystallizes in monoclinic system, space group C2/c. In 1, the Cu(II) ions are further joined by picolinic acid ligands, generating 1D coordination polymer running parallel to the [100] direction, while the Cu(II) ions are further joined by sulfate ligands, generating 1D coordination polymer running parallel to the [001] direction in 2. Notably, the 2-Hpyc ligand is in situ generated by decarboxylation of the 2,6-pyridinedicarboxylic (2,6-pydc) acid ligand under hydrothermal conditions. Thermal stability, luminescence and electrical conductivity properties of 1 and 2 have been investigated.
dc.description.sponsorshipResearch Unit of Cukurova University [FBA-2018-10200]
dc.description.sponsorshipThe authors gratefully acknowledge financial support from the Research Unit of Cukurova University (Grant No. FBA-2018-10200). The authors acknowledge to Scientific and Technological Research Application and Research Centre, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1016/j.solidstatesciences.2019.105958
dc.identifier.issn1293-2558
dc.identifier.issn1873-3085
dc.identifier.scopus2-s2.0-85070506108
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.solidstatesciences.2019.105958
dc.identifier.urihttps://hdl.handle.net/11486/6031
dc.identifier.volume96
dc.identifier.wosWOS:000487809800016
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofSolid State Sciences
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectHydrothermal synthesis
dc.subjectCoordination polymers
dc.subjectIn-situ decarboxylation
dc.subjectElectrical conductivity
dc.subjectLuminescence
dc.titleOne-Pot hydrothermal synthesis of 1D copper (II) coordination polymers involving in-situ decarboxylation
dc.typeArticle

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