Heteronuclear coordination polymers with imidazole ligand: Synthesis, characterization and alcohol oxidation activities

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dc.contributor.authorKurkcuoglu, Guenes Suheyla
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorMwanza, Telvin
dc.contributor.authorKekec, Seray
dc.contributor.authorUnver, Hakan
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:38:17Z
dc.date.available2025-03-23T19:38:17Z
dc.date.issued2024
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new heteronuclear Cd(II)/Pd(II) coordination polymers, [Cd2(mu -im)2(Him)4Pd(mu -CN)4]n (1) and [Cd (Him)2Pd(mu -CN)4]n (2) (Him: imidazole), have been synthesized under different conditions and characterized using elemental analysis, thermal analysis, FT-IR and Raman spectroscopy, single-crystal and powder X-ray diffraction techniques. In 1, the Cd(II) ions are bridged by imidazolate ligands to generate 1D chain structure. Neighbouring 1D chains were linked by [Pd(CN)4]2- ions to form 3D framework. In 2, the metal ions are bridged by cyanide ligands to generate 2D [Cd2Pd2(mu -CN)4]n network. Catalytic peroxidative oxidation activity of 1 and 2 was examined on the oxidation of benzyl alcohol using tertiary-butyl hydroperoxide (t-BuOOH) as the oxygen source. The compound 1 exhibited over 90 % product conversion at 80 degrees C in 24-hour reaction time. In addition, the catalyst exhibited high selectivity towards benzaldehyde and no over-oxidation product (benzoic acid) was detected.
dc.description.sponsorshipEskisehir Osmangazi University, Scientific research Unit [2022-2561]; Eskisehir Technical University Scientific Research Projects Commission [22ADP124]
dc.description.sponsorshipThis work has been financially supported by Eskisehir Osmangazi University, Scientific research Unit (Grant No: 2022-2561) . This study was supported by Eskisehir Technical University Scientific Research Projects Commission under grant no: 22ADP124.
dc.identifier.doi10.1016/j.poly.2024.117263
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.scopus2-s2.0-85207373942
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.poly.2024.117263
dc.identifier.urihttps://hdl.handle.net/11486/6114
dc.identifier.volume264
dc.identifier.wosWOS:001348607100001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectTetracyanopalladate(II) complex
dc.subjectCadmium(II) complex
dc.subjectImidazole complex
dc.subject3D coordination polymer
dc.subjectAlcohol oxidation
dc.titleHeteronuclear coordination polymers with imidazole ligand: Synthesis, characterization and alcohol oxidation activities
dc.typeArticle

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