Fabrication and characterization of magnesium and calcium trimesate complexes via ion-exchange and one-pot self-assembly reaction

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dc.authoridOZER, Demet/0000-0003-0862-9607
dc.contributor.authorOzer, Demet
dc.contributor.authorOztas, Nursen Altuntas
dc.contributor.authorKose, Dursun A.
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:39:37Z
dc.date.available2025-03-23T19:39:37Z
dc.date.issued2018
dc.departmentSinop Üniversitesi
dc.description.abstractUsing two different synthesis methods, two diversified magnesium and calcium complexes were successfully prepared. When the ion exchange method was used, C9H14MgO11 center dot H2O and G(18)H(30)Ca(3)O(24) complexes were obtained. When the one-pot self-assembly reaction was used, C18H34Mg3O26 center dot 4H(2)O and C9H12CaO10 complexes were produced. The structural characterizations were performed by using X-ray diffraction, FT-IR and elemental analyses. Thermal behavior of complexes were also determined via TGA method. The both complexes of magnesium and calcium trimesate have micro and mesoporosity with low porosity because of hydrogen bonds. Then hydrogen storage capacities of complexes were also determined. The differences in synthesis method result in the differences on complexes structure, morphology (shape, particle size and specific surface area) and hydrogen storage capacities. (C) 2017 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2017.11.128
dc.identifier.endpage359
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85036474372
dc.identifier.scopusqualityQ1
dc.identifier.startpage353
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.11.128
dc.identifier.urihttps://hdl.handle.net/11486/6390
dc.identifier.volume1156
dc.identifier.wosWOS:000425075900041
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCalcium trimesate
dc.subjectMagnesium trimesate
dc.subjectMOF
dc.subjectIon exchange
dc.subjectOne-pot self-assembly reaction
dc.titleFabrication and characterization of magnesium and calcium trimesate complexes via ion-exchange and one-pot self-assembly reaction
dc.typeArticle

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