Diagnostic and control of linear and nonlinear optical effects in selected self-assembled metallophthalocyanine chlorides nanostructures

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dc.authoridSAHRAOUI, Bouchta/0000-0002-3934-2839
dc.authoridZawadzka, Anna/0000-0002-1599-5675
dc.authoridKARAKAS, ASLI/0000-0002-9034-5840
dc.authoridWaszkowska, Karolina/0000-0003-0746-7327
dc.authoridKarakaya, Mustafa/0000-0001-6663-9008
dc.authoridWisniewski, Krzysztof/0000-0003-0681-7727
dc.contributor.authorZawadzka, A.
dc.contributor.authorWaszkowska, K.
dc.contributor.authorKarakas, A.
dc.contributor.authorPlociennik, P.
dc.contributor.authorKorcala, A.
dc.contributor.authorWisniewski, K.
dc.contributor.authorKarakaya, M.
dc.date.accessioned2025-03-23T19:41:46Z
dc.date.available2025-03-23T19:41:46Z
dc.date.issued2018
dc.departmentSinop Üniversitesi
dc.description.abstractIn this paper we described a new self-assembly phenomenon of the metallophthalocyanine chlorides nanostructures and its influence on the linear optical properties as well as the Second Harmonic Generation process. The self-assembly phenomenon were achieved through an annealing process carried out immediately after the deposition process. The studied nanostructures were subjected to the annealing process for 24 h and the temperature of the process was equal to 525 K. We discussed experimental results and theoretical calculations of structural, linear and nonolinear optical properties for aluminum and gallium phthalocyanine chlorides. The linear and second-order nonlinear optical properties for these compounds were investigated at microscopic and macroscopic levels. The electric dipole moments and dispersion-free first hyperpolarizabilities were determined by quantum chemical calculations based on Density Functional Theory. Ab-initio quantum mechanical calculations (time-dependent Hartree-Fock method) for the studied metallophthalocyanine chlorides were carried out to compute the frequency-dependent first hyperpolarizabilities and second-order susceptibilities at the wavelengths used in SHG measurements. Our results shed light on the linear and nonlinear optical properties of the nanostructures. The results showed that second harmonic signal is strong and polarized, and this polarizing effect was achieved by controlling the arrangement of the molecules inside the formed nanostructures. Our results also reveal potential application of the nanostructures not only for nonlinear optics but also for thermal sensor devices.
dc.description.sponsorshipPolish National Science Centre [2017/25/B/ST7/02124]; COST Action Nanoscale Quantum Optics [MP1403]
dc.description.sponsorshipThis research has been financed from the funds of the Polish National Science Centre (grant no. 2017/25/B/ST7/02124). The films used in this paper were obtained using Interdisciplinary Centre for Modern Technologies facilities, NCU, Torun, Poland. The authors wish to thank the COST Action MP1403 Nanoscale Quantum Optics.
dc.identifier.doi10.1016/j.dyepig.2018.04.048
dc.identifier.endpage162
dc.identifier.issn0143-7208
dc.identifier.issn1873-3743
dc.identifier.scopus2-s2.0-85046357826
dc.identifier.scopusqualityQ1
dc.identifier.startpage151
dc.identifier.urihttps://doi.org/10.1016/j.dyepig.2018.04.048
dc.identifier.urihttps://hdl.handle.net/11486/6641
dc.identifier.volume157
dc.identifier.wosWOS:000437813700019
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofDyes and Pigments
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectMetallophthalocyanine chlorides
dc.subjectSelf-assembed nanostructures
dc.subjectSHG spectroscopy
dc.subjectPhotoluminescence
dc.subjectDensity functional theory
dc.subjectAb-initio time-dependent Hartree-Fock method
dc.titleDiagnostic and control of linear and nonlinear optical effects in selected self-assembled metallophthalocyanine chlorides nanostructures
dc.typeArticle

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