One dimensional coordination polymers: Synthesis, crystal structures and spectroscopic properties

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dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorKaraagac, Dursun
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorSenyel, Mustafa
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:40:46Z
dc.date.available2025-03-23T19:40:46Z
dc.date.issued2016
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new one dimensional (1D) cyanide complexes, namely [M(4-aepy)(2)(H2O)(2)][Pt(CN)(4)], (4-aepy = 4-(2-aminoethyl)pyridine M = Cu(II) (1) or Zn(II) (2)), have been synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal and elemental analyses techniques. The crystallographic analyses reveal that 1 and 2 are isomorphous and isostructural, and crystallize in the monoclinic system and C2 space group. The Pt(II) ions are coordinated by four cyanide-carbon atoms in the square-planar geometry and the [Pt(CN)4]2 ions act as a counter ion. The M(II) ions display an N4O2 coordination sphere with a distorted octahedral geometry, the nitrogen donors belonging to four molecules of the organic 4-aepy that act as unidentate ligands and two oxygen atoms from aqua ligands. The crystal structures of 1 and 2 are similar each other and linked via intermolecular hydrogen bonding, Pt center dot center dot center dot pi interactions to form 3D supramolecular network. Vibration assignments of all the observed bands are given and the spectral features also supported to the crystal structures of the complexes. (C) 2016 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2016.06.036
dc.identifier.endpage334
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-84975883400
dc.identifier.scopusqualityQ1
dc.identifier.startpage327
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2016.06.036
dc.identifier.urihttps://hdl.handle.net/11486/6406
dc.identifier.volume1123
dc.identifier.wosWOS:000381833100038
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectTetracyanoplatinate(II) complex
dc.subjectCopper(II) complex
dc.subjectZinc(II) complex
dc.subject4-(2-Aminoethyl)pyridine complex
dc.subjectVibrational spectra
dc.subjectCrystal structure
dc.titleOne dimensional coordination polymers: Synthesis, crystal structures and spectroscopic properties
dc.typeArticle

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