Synthesis, Crystal Structures of Gadolinium(III) and Erbium(III) Complexes Derived from Pyridine-2,6-Dicarboxylic Acid and Fluorescent Sensing of Picric Acid

Basit Öğe Kaydı
dc.authoridAdnan, Ahmad/0000-0001-7114-8916
dc.contributor.authorSharif, S.
dc.contributor.authorZaheer, S.
dc.contributor.authorMumtaz, M. W.
dc.contributor.authorSahin, O.
dc.contributor.authorAhmad, S.
dc.contributor.authorZulfiqar, S.
dc.contributor.authorAdnan, A.
dc.date.accessioned2025-03-23T19:31:37Z
dc.date.available2025-03-23T19:31:37Z
dc.date.issued2021
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new complexes of gadolinium(III) and erbium(III) with pyridine-2,6-dicarboxylic acid (H(2)Pydc),{Na-3[Gd(Pydc)(3)]center dot 2H(2)O}(n) (I) and [Er(HPydc)(3)]center dot 10H(2)O (II), were prepared and their crystal structures were determined by X-ray crystallography (CIF files CCDC nos. 940633 (I) and 872068 (II)). The gadolinium atom in I is nine-coordinate (GdN3O6) and exhibits a tricapped trigonal prismatic geometry having 14 triangular faces. The Pydc ligand adopts chelating and, mu(3)- and mu(5)-bridging coordination modes. The 1D chains are further joined by Na atoms to generate a 3D coordination polymer. The structure is additionally stabilized by H-bonding. The Erbium polyhedron in II is also a tricapped trigonal prism (ErN3O6). The HPydc anions in II behave as tridentate chelating ligands. The complex molecules are connected to each other through hydrogen bonding interactions to form a three-dimensional network. Fluorescence titration experiments for complex II displayed highly sensitive fluorescence quenching efficiency of 98.3% against picric acid.
dc.description.sponsorshipHigher Education Commission of Pakistan, HEC project [01-ISULL/09/GCUL/ACAD/HEC/2017/166]; Office of Research Innovation and Commercialization GC University, Lahore, ORIC project [108/ORIC/19]
dc.description.sponsorshipWe gratefully acknowledge financial assistance from Higher Education Commission of Pakistan, HEC project no. 01-ISULL/09/GCUL/ACAD/HEC/2017/166 and Office of Research Innovation and Commercialization GC University, Lahore, ORIC project no. 108/ORIC/19.
dc.identifier.doi10.1134/S1070328420120076
dc.identifier.endpage104
dc.identifier.issn1070-3284
dc.identifier.issn1608-3318
dc.identifier.issue1
dc.identifier.scopus2-s2.0-85100838721
dc.identifier.scopusqualityQ3
dc.identifier.startpage95
dc.identifier.urihttps://doi.org/10.1134/S1070328420120076
dc.identifier.urihttps://hdl.handle.net/11486/5321
dc.identifier.volume47
dc.identifier.wosWOS:000617822200013
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPleiades Publishing Inc
dc.relation.ispartofRussian Journal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectgadolinium(III)
dc.subjecterbium(III)
dc.subjectpyridine-2
dc.subject6-dicarboxylate
dc.subjectcrystal structure
dc.subjectfluorescence quenching
dc.titleSynthesis, Crystal Structures of Gadolinium(III) and Erbium(III) Complexes Derived from Pyridine-2,6-Dicarboxylic Acid and Fluorescent Sensing of Picric Acid
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu