The imidazo{[4,5-f][1,10]-phenanthrolin}l-2-ylidene and its palladium complexes: Synthesis, characterization, and application in C-C cross-coupling reactions

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dc.authoridSAHIN, ZARIFE SIBEL/0000-0003-2745-7871
dc.authoridturkmen, hayati/0000-0001-7411-2652
dc.authoridPelit, Levent/0000-0001-8090-703X
dc.contributor.authorGok, Lutfiye
dc.contributor.authorGunnaz, Salih
dc.contributor.authorSahin, Zarife Sibel
dc.contributor.authorPelit, Levent
dc.contributor.authorTurkmen, Hayati
dc.date.accessioned2025-03-23T19:40:59Z
dc.date.available2025-03-23T19:40:59Z
dc.date.issued2017
dc.departmentSinop Üniversitesi
dc.description.abstract1,3-dibutyl-1H-imidazo[4,5-f][1,10]phenanthrolinium iodide, L-5 center dot 2HI ligand and their mono-, di-, tri-, tetra-nuclear palladium(II) complexes (5 center dot HPF6, 6-8) were synthesized and characterized by elemental analysis, FTIR, UV-visible and NMR spectroscopy. In addition, the complexes (5 center dot HPF6, 6-8) were determined by mass spectrometry (MALDI). The ligand L-5 center dot 2HI was determined by X-ray diffraction. The complexes (5 center dot HPF6, 6-8) were tested in Suzuki-Miyaura and Mizoroki-Heck reactions at elevated temperatures. The activities of the catalysts were monitored by NMR and GC analysis. We found that the poly-nuclear complexes display better activities compared to the mono-nuclear derivatives, thus proposing that an increase in metal moieties which leads to an increase in activity in cross-coupling reaction. (C) 2016 Elsevier B.V. All rights reserved.
dc.description.sponsorshipEge University [2012-BIL-042, 2013 FEN 062]; TUBITAK [111T398]
dc.description.sponsorshipWe sincerely thank to Prof. Dr. Samil Isik for his help with the data collection. Thanks to Biological Mass Spectrometry and Proteomics Laboratory at IYTE Chemistry Department for their help with mass measurements. Financial support from Ege University (Project 2012-BIL-042; 2013 FEN 062) and TUBITAK (111T398) is gratefully acknowledged.
dc.identifier.doi10.1016/j.jorganchem.2016.11.013
dc.identifier.endpage104
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-84995426446
dc.identifier.scopusqualityQ2
dc.identifier.startpage96
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2016.11.013
dc.identifier.urihttps://hdl.handle.net/11486/6485
dc.identifier.volume827
dc.identifier.wosWOS:000389610700011
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal of Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectImidazo{[4,5-f][1,10]-phenanthrolin}l-2-ylidene
dc.subjectPalladium
dc.subjectSuzuki-Miyaura coupling
dc.subjectMizoroki-Heck coupling
dc.titleThe imidazo{[4,5-f][1,10]-phenanthrolin}l-2-ylidene and its palladium complexes: Synthesis, characterization, and application in C-C cross-coupling reactions
dc.typeArticle

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